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With a selectivity of 84.5\u2009%, a reaction rate of 782\u2005mmol\u2009h<jats:sup>\u22121<\/jats:sup>\u2009m<jats:sup>\u22122<\/jats:sup> and a CE of 32\u2009% (for 0.09\u2009<jats:sc>m<\/jats:sc> hydroxyacetone), iron electrodes, in a chloride electrolyte, yielded the best 1,2 propanediol formation. A further enhancement of the performance can be achieved upon increasing the educt concentration to 0.5\u2009<jats:sc>m<\/jats:sc>, yielding a reaction rate of 2248.1\u2005mmol\u2009h<jats:sup>\u22121<\/jats:sup>\u2009m<jats:sup>\u22122<\/jats:sup> and a CE of 64.5\u2009%. Acetone formation was optimal at copper and lead electrodes in chloride solution, with lead showing the lowest tendency of side product formation. 2\u2010propanol formation can be achieved using a consecutive oxidation of the formed acetone (at iron electrodes). 1\u2010propanol formation was observed only in traces.<\/jats:p>","DOI":"10.1002\/cssc.201700996","type":"journal-article","created":{"date-parts":[[2017,6,23]],"date-time":"2017-06-23T06:53:22Z","timestamp":1498200802000},"page":"3105-3110","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Hydroxyacetone: A Glycerol\u2010Based Platform for Electrocatalytic Hydrogenation and Hydrodeoxygenation Processes"],"prefix":"10.1002","volume":"10","author":[{"given":"Waldemar","family":"Sauter","sequence":"first","affiliation":[{"name":"Institute of Environmental and Sustainable Chemistry Technische Universit\u00e4t Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olaf L.","family":"Bergmann","sequence":"additional","affiliation":[{"name":"Institute of Environmental and Sustainable Chemistry Technische Universit\u00e4t Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Uwe","family":"Schr\u00f6der","sequence":"additional","affiliation":[{"name":"Institute of Environmental and Sustainable Chemistry Technische Universit\u00e4t Braunschweig  Hagenring 30 38106 Braunschweig Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,7,20]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"J.\u2005E. 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