{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T04:03:45Z","timestamp":1790222625184,"version":"4.1.0"},"reference-count":37,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2017,9,21]],"date-time":"2017-09-21T00:00:00Z","timestamp":1505952000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2017,10,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Perovskite solar cells, as an emergent technology for solar energy conversion, have attracted much attention in the solar cell community by demonstrating impressive enhancement in power conversion efficiencies. However, the high temperature and manually processed TiO<jats:sub>2<\/jats:sub> underlayer prepared by spray pyrolysis significantly limit the large\u2010scale application and device reproducibility of perovskite solar cells. In this study, lowtemperature atomic layer deposition (ALD) is used to prepare a compact Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> underlayer for perovskite solar cells. The thickness of the Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> layer can be controlled well by adjusting the deposition cycles during the ALD process. An optimal Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> layer effectively blocks electron recombination at the perovskite\/fluorine\u2010doped tin oxide interface and sufficiently transports electrons through tunneling. Perovskite solar cells fabricated with an Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> layer demonstrated a highest efficiency of 16.2\u2009% for the sample with 50 ALD cycles (ca.\u20055\u2005nm), which is a significant improvement over underlayer\u2010free PSCs, which have a maximum efficiency of 11.0\u2009%. Detailed characterization confirms that the thickness of the Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> underlayer significantly influences the charge transfer resistance and electron recombination processes in the devices. Furthermore, this work shows the feasibility of using a high band\u2010gap semiconductor such as Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> as the underlayer in perovskite solar cells and opens up pathways to use ALD Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> underlayers for flexible solar cells.<\/jats:p>","DOI":"10.1002\/cssc.201701160","type":"journal-article","created":{"date-parts":[[2017,8,31]],"date-time":"2017-08-31T08:04:19Z","timestamp":1504166659000},"page":"3810-3817","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["Al<sub>2<\/sub>O<sub>3<\/sub> Underlayer Prepared by Atomic Layer Deposition for Efficient Perovskite Solar Cells"],"prefix":"10.1002","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6078-4404","authenticated-orcid":false,"given":"Jinbao","family":"Zhang","sequence":"first","affiliation":[{"name":"Physical Chemistry, Centre of Molecular Devices Department of Chemistry, \u00c5ngstr\u00f6m Laboratory Uppsala University  SE-75120 Uppsala Sweden"},{"name":"Department of Materials Engineering Monash University  Clayton Victoria 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adam","family":"Hultqvist","sequence":"additional","affiliation":[{"name":"\u00c5ngstr\u00f6m Solar Center, Solid State Electronics, Department of Engineering Sciences Uppsala University  Box 534 SE-751 21 Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering Monash University  Clayton Victoria 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liangcong","family":"Jiang","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering Monash University  Clayton Victoria 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changqing","family":"Ruan","sequence":"additional","affiliation":[{"name":"Nanotechnology and Functional Materials Department of Engineering Science Uppsala University  SE-75120 Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Yang","sequence":"additional","affiliation":[{"name":"Nanotechnology and Functional Materials Department of Engineering Science Uppsala University  SE-75120 Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yibing","family":"Cheng","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering Monash University  Clayton Victoria 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marika","family":"Edoff","sequence":"additional","affiliation":[{"name":"\u00c5ngstr\u00f6m Solar Center, Solid State Electronics, Department of Engineering Sciences Uppsala University  Box 534 SE-751 21 Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9358-8277","authenticated-orcid":false,"given":"Erik M. 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