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Etherification of 5\u2010(hydroxymethyl)furfural with different aliphatic alcohols over acidic Zr\u2013montmorillonite (Zr\u2010Mont) catalyst produced a mixture of 5\u2010(alkoxymethyl)furfural and 2\u2010(dialkoxymethyl)\u20105\u2010(alkoxymethyl)furan. The latter was selectively converted back into 5\u2010(alkoxymethyl)furfural by treating it with water over the same catalyst. The synthesis of 2,5\u2010bis(alkoxymethyl)furan was achieved through a cascade sequence involving etherification, transfer hydrogenation, and re\u2010etherification over a combination of acidic Zr\u2010Mont and the charge\u2010transfer hydrogenation catalyst [ZrO(OH)<jats:sub>2<\/jats:sub>]. This catalyst combination was further explored for the cascade conversion of 2\u2010furfuraldehyde into 2\u2010(alkoxymethyl)furan. The scope of this strategy was then extended for the reductive etherification of lignin\u2010derived arylaldehydes to obtain the respective benzyl ethers in &gt;80\u2009% yield. Additionally, the mixture of Zr\u2010Mont and ZrO(OH)<jats:sub>2<\/jats:sub> does not undergo mutual destruction, which was proved by recycling experiments and XRD analysis. Both the catalysts were thoroughly characterized using BET, temperature\u2010programmed desorption of NH<jats:sub>3<\/jats:sub> and CO<jats:sub>2<\/jats:sub>, pyridine\u2010FTIR, XRD, inductively coupled plasma optical emission spectroscopy, and X\u2010ray photoelectron spectroscopy techniques.<\/jats:p>","DOI":"10.1002\/cssc.201701275","type":"journal-article","created":{"date-parts":[[2017,9,4]],"date-time":"2017-09-04T04:26:40Z","timestamp":1504499200000},"page":"4090-4101","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":69,"title":["Cascade Reductive Etherification of Bioderived Aldehydes over Zr\u2010Based Catalysts"],"prefix":"10.1002","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3135-6459","authenticated-orcid":false,"given":"Suhas","family":"Shinde","sequence":"first","affiliation":[{"name":"Chemical Engineering and Process Development Division CSIR National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2093-2708","authenticated-orcid":false,"given":"Chandrashekhar","family":"Rode","sequence":"additional","affiliation":[{"name":"Chemical Engineering and Process Development Division CSIR National Chemical Laboratory  Dr. Homi Bhabha Road Pune 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,10,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c004343e"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100448"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/b922014c"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1111166"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/B921306F"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature05923"},{"key":"e_1_2_7_7_1","unstructured":"\u00a0"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300182k"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201100035"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1gc15047b"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2gc35039d"},{"key":"e_1_2_7_12_1","unstructured":"\u00a0"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801594"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801594"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.carres.2011.12.006"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2013.06.015"},{"key":"e_1_2_7_16_1","unstructured":"\u00a0"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100489"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2gc35102a"},{"key":"e_1_2_7_19_1","unstructured":"\u00a0"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2012.04.049"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2012.06.001"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc41109e"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2011.05.008"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201300301"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA06135G"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2015.02.020"},{"key":"e_1_2_7_27_1","unstructured":"\u00a0"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie2025536"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ra20574b"},{"key":"e_1_2_7_30_1","unstructured":"G. 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