{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T14:33:16Z","timestamp":1783607596027,"version":"3.55.0"},"reference-count":77,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2017,10,5]],"date-time":"2017-10-05T00:00:00Z","timestamp":1507161600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21672227"],"award-info":[{"award-number":["21672227"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["XDB17030400"],"award-info":[{"award-number":["XDB17030400"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2017,11,23]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Heterogeneous visible\u2010light photocatalysis represents an important route toward the development of sustainable organic synthesis. In this study visible light\u2010induced, heavy metal\u2010free atom\u2010transfer radical addition to unactivated terminal olefins is carried out by using the combination of heterogeneous titanium dioxide as photocatalyst and a hypervalent iodine(III) reagent as co\u2010initiator. The reaction can be applied to a range of substrates with good functional\u2010group tolerance under very mild conditions. In addition to a number of commonly used atom\u2010transfer reagents, the relatively challenging chloroform is also suitable.<\/jats:p>","DOI":"10.1002\/cssc.201701382","type":"journal-article","created":{"date-parts":[[2017,9,9]],"date-time":"2017-09-09T01:36:38Z","timestamp":1504920998000},"page":"4461-4464","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Atom\u2010Transfer Radical Addition to Unactivated Alkenes by using Heterogeneous Visible\u2010Light Photocatalysis"],"prefix":"10.1002","volume":"10","author":[{"given":"Liang\u2010Liang","family":"Mao","sequence":"first","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing 100190 P.R. China"},{"name":"School of Future Technology University of Chinese Academy of Sciences  Beijing 100190 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1687-2404","authenticated-orcid":false,"given":"Huan","family":"Cong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing 100190 P.R. China"},{"name":"School of Future Technology University of Chinese Academy of Sciences  Beijing 100190 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,10,5]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.102.2640.128.a"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01183a053"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00269a016"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00274a034"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00206a016"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00181a057"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00008a032"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo981774p"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0014281"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo010652l"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100379"},{"key":"e_1_2_2_13_1","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja108560e"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300798k"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0033-1338910"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201406450"},{"key":"e_1_2_2_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201406450"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201403466"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201412199"},{"key":"e_1_2_2_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201412199"},{"key":"e_1_2_2_20_1","unstructured":"\u00a0"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00214"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00272"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00229"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00254"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00275"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00351"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00280"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00057"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b01449"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00185H"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0052"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01385"},{"key":"e_1_2_2_33_1","unstructured":"\u00a0"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/B913880N"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b01058"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00296"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00248"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00270"},{"key":"e_1_2_2_39_1","unstructured":"\u00a0"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.6023\/cjoc201605034"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.7b00148"},{"key":"e_1_2_2_42_1","unstructured":"\u00a0"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja709989e"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108721"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108721"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201200"},{"key":"e_1_2_2_45_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201201200"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201207199"},{"key":"e_1_2_2_46_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201207199"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307374"},{"key":"e_1_2_2_47_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307374"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1071\/CH15322"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b03687"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206566"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201206566"},{"key":"e_1_2_2_51_1","unstructured":"The reaction completely stopped upon removal of light source and resumed when the LED was reintroduced (see the Supporting Information Figure\u2005S2)."},{"key":"e_1_2_2_52_1","unstructured":"CCDC\u20051563279 (3\u2009p) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge fromThe Cambridge Crystallographic Data Centre."},{"key":"e_1_2_2_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp010309k"},{"key":"e_1_2_2_54_1","unstructured":"\u00a0"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200500321"},{"key":"e_1_2_2_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt01764g"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201301849"},{"key":"e_1_2_2_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar50153a004"},{"key":"e_1_2_2_59_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60188A"},{"key":"e_1_2_2_60_1","unstructured":"We propose that the interaction between Togni reagent\u2005I and TiO2leads to a modified surface that can absorb visible light as supported by results of solid-state UV\/Vis spectroscopy (Figure\u2005S4). Related modifications of TiO2surfaces by small organic molecules have been reported. Selected examples include:"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201103242"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102779"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc40587g"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00668"},{"key":"e_1_2_2_65_1","unstructured":"\u00a0"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201412310"},{"key":"e_1_2_2_66_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201412310"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01301"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b10468"},{"key":"e_1_2_2_69_1","doi-asserted-by":"publisher","DOI":"10.1039\/b921692h"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201701382","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201701382","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T07:48:23Z","timestamp":1760341703000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201701382"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,10,5]]},"references-count":77,"journal-issue":{"issue":"22","published-print":{"date-parts":[[2017,11,23]]}},"alternative-id":["10.1002\/cssc.201701382"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201701382","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,10,5]]},"assertion":[{"value":"2017-07-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2017-10-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}