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Although several functional porous nanostructures have been developed, high\u2010efficiency materials are still needed. Herein, we report a new, highly active, noble\u2010metal\u2010free, and redox\u2010mediator\u2010free Z\u2010scheme photocatalyst, CdS\/Co\u2010C@Co<jats:sub>9<\/jats:sub>S<jats:sub>8<\/jats:sub>, for H<jats:sub>2<\/jats:sub> production through water splitting under solar irradiation. The designed photocatalytic system contains open 3\u2009D CdS mesopores as a light absorber for wider solar\u2010light harvesting. Metal\u2013organicframework\u2010derived cobalt nanocrystal\u2010embedded few\u2010layered carbon@Co<jats:sub>9<\/jats:sub>S<jats:sub>8<\/jats:sub> double\u2010shelled nanocages were used as a co\u2010semiconductor to hamper the photo charge\u2010carrier recombination by accelerating the photogenerated electrons and holes from the other semiconductor. The optimized catalyst shows a H<jats:sub>2<\/jats:sub> evolution rate of 26.69\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup> under simulated solar irradiation, which is 46\u2005times higher than that of the as\u2010synthesized CdS mesoporous nanostructures. The apparent quantum yield reached 7.82\u2009% at <jats:italic>\u03bb<\/jats:italic>=425\u2005nm in 5\u2005h. The outstanding photocatalytic activity of CdS\/Co\u2010C@Co9S8 reflects the favorable suppression of the charge\u2010carrier recombination rate, as determined by photoluminescence, photocurrent, and impedance analyses. We believe that the findings reported here may inspire the design of new noble\u2010metal\u2010free porous nanohybrids for sustainable H<jats:sub>2<\/jats:sub> production.<\/jats:p>","DOI":"10.1002\/cssc.201701643","type":"journal-article","created":{"date-parts":[[2017,10,3]],"date-time":"2017-10-03T08:36:37Z","timestamp":1507019797000},"page":"245-253","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":84,"title":["Designing CdS Mesoporous Networks on Co\u2010C@Co<sub>9<\/sub>S<sub>8<\/sub> Double\u2010Shelled Nanocages as Redox\u2010Mediator\u2010Free Z\u2010Scheme Photocatalyst"],"prefix":"10.1002","volume":"11","author":[{"given":"D. Amaranatha","family":"Reddy","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanbit","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Madhusudana","family":"Gopannagari","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eun Hwa","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seunghee","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Institute for Functional Materials Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"D. 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