{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T02:25:03Z","timestamp":1790475903910,"version":"4.1.0"},"reference-count":57,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2017,11,23]],"date-time":"2017-11-23T00:00:00Z","timestamp":1511395200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2018,1,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The room\u2010temperature molten salt mixture of <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2010diethyl\u2010<jats:italic>N\u2010(<\/jats:italic>2\u2010methoxyethyl)\u2010<jats:italic>N<\/jats:italic>\u2010methylammonium bis(trifluoromethanesulfonyl) imide ([DEME][TFSI]) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is herein reported as electrolyte for application in Li\u2013O<jats:sub>2<\/jats:sub> batteries. The [DEME][TFSI]\u2013LiTFSI solution is studied in terms of ionic conductivity, viscosity, electrochemical stability, and compatibility with lithium metal at 30\u2009\u00b0C, 40\u2009\u00b0C, and 60\u2009\u00b0C. The electrolyte shows suitable properties for application in Li\u2013O<jats:sub>2<\/jats:sub> battery, allowing a reversible, low\u2010polarization discharge\u2013charge performance with a capacity of about 13\u2005Ah\u2005g<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/cssc201701696-math-0001.png\" xlink:title=\"urn:x-wiley:18645631:media:cssc201701696:cssc201701696-math-0001\"\/>\n in the positive electrode and coulombic efficiency approaching 100\u2009%. The reversibility of the oxygen reduction reaction (ORR)\/oxygen evolution reaction (OER) is demonstrated by ex\u2005situ XRD and SEM studies. Furthermore, the study of the cycling behavior of the Li\u2013O<jats:sub>2<\/jats:sub> cell using the [DEME][TFSI]\u2010LiTFSI electrolyte at increasing temperatures (from 30 to 60\u2009\u00b0C) evidences enhanced energy efficiency together with morphology changes of the deposited species at the working electrode. In addition, the use of carbon\u2010coated Zn<jats:sub>0.9<\/jats:sub>Fe<jats:sub>0.1<\/jats:sub>O (TMO\u2010C) lithium\u2010conversion anode in an ionic\u2010liquid\u2010based Li\u2010ion\/oxygen configuration is preliminarily demonstrated.<\/jats:p>","DOI":"10.1002\/cssc.201701696","type":"journal-article","created":{"date-parts":[[2017,9,29]],"date-time":"2017-09-29T12:41:30Z","timestamp":1506688890000},"page":"229-236","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["Low\u2010Polarization Lithium\u2013Oxygen Battery Using [DEME][TFSI] Ionic Liquid Electrolyte"],"prefix":"10.1002","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8345-8185","authenticated-orcid":false,"given":"Ulderico","family":"Ulissi","sequence":"first","affiliation":[{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstrasse\u200511 89081 Ulm Germany"},{"name":"Karlsruhe Institute of Technology (KIT)  P.O. Box\u20053640 76021 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6790-1143","authenticated-orcid":false,"given":"Giuseppe Antonio","family":"Elia","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Berlin Fakult\u00e4t IV Elektrotechnik und Informatik Fraunhofer IZM  Gustav-Meyer-Allee\u200525 13355 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sangsik","family":"Jeong","sequence":"additional","affiliation":[{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstrasse\u200511 89081 Ulm Germany"},{"name":"Karlsruhe Institute of Technology (KIT)  P.O. Box\u20053640 76021 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franziska","family":"Mueller","sequence":"additional","affiliation":[{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstrasse\u200511 89081 Ulm Germany"},{"name":"Karlsruhe Institute of Technology (KIT)  P.O. Box\u20053640 76021 Karlsruhe Germany"},{"name":"Institute of Physical Chemistry University of Muenster  Corrensstr.\u200528\/30 48149 Muenster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jakub","family":"Reiter","sequence":"additional","affiliation":[{"name":"BMW Group  Petuelring\u2005130 80788 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolaos","family":"Tsiouvaras","sequence":"additional","affiliation":[{"name":"BMW Group  Petuelring\u2005130 80788 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang\u2010Kook","family":"Sun","sequence":"additional","affiliation":[{"name":"Department of Energy Engineering Hanyang University  Seoul 133-791 South Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bruno","family":"Scrosati","sequence":"additional","affiliation":[{"name":"Elettrochimica ed Energia  00199 Rome Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefano","family":"Passerini","sequence":"additional","affiliation":[{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstrasse\u200511 89081 Ulm Germany"},{"name":"Karlsruhe Institute of Technology (KIT)  P.O. Box\u20053640 76021 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8218-5680","authenticated-orcid":false,"given":"Jusef","family":"Hassoun","sequence":"additional","affiliation":[{"name":"Department of Chemical and Pharmaceutical Sciences University of Ferrara  Via Fossato di Mortara 44121 Ferrara Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,11,23]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201403064"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2013.12.004"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3237"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz1005384"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz200352v"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz300243r"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2021747"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja302178w"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2132"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC04620C"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3737"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2017.06.137"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40998h"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp4099478"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp304277z"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl5031985"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b04950"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2013.05.147"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1ee01388b"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.010201eel"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2426871"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2010.06.005"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2011.10.036"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/ente.201402226"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2014.10.089"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp911759d"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm403443t"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500003w"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/je900878j"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/0471762512"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE01295G"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/bk-2012-1117.ch004"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr030203g"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(00)00431-6"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2006.10.025"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/am3026129"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ra20536j"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(86)90100-1"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(86)90031-7"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.3390\/ijms15058122"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2013.12.099"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4041"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2016.11.220"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201502164"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz301359t"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500054y"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1376"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc44723e"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.3555366"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201200810"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-2738(02)00080-2"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2260"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2138"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl303087j"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b07414"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA03013K"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201701696","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201701696","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T19:09:35Z","timestamp":1760382575000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201701696"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,11,23]]},"references-count":57,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2018,1,10]]}},"alternative-id":["10.1002\/cssc.201701696"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201701696","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,11,23]]},"assertion":[{"value":"2017-09-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2017-11-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}