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The results are compared with their zirconium\u2010based counterparts. The role of the metal center in Hf\u2010MOFs has been identified and reaction parameters optimized. NMR studies using isotopically labeled isopropanol provide evidence that the transfer hydrogenation occurs through a direct intermolecular hydrogen transfer route. The catalyst, Hf\u2010MOF\u2010808, can be recycled several times with only a minor decrease in catalytic activity. The generality of the procedure has been demonstrated by accomplishing the transformation with aldehydes, ketones, and \u03b1,\u03b2\u2010unsaturated carbonyl compounds. The combination of Hf\u2010MOF\u2010808 with the Br\u00f8nsted\u2010acidic Al\u2010Beta zeolite gives the four\u2010step one\u2010pot transformation of furfural to \u03b3\u2010valerolactone in good yield of 75\u2009%.<\/jats:p>","DOI":"10.1002\/cssc.201701708","type":"journal-article","created":{"date-parts":[[2017,11,15]],"date-time":"2017-11-15T06:52:40Z","timestamp":1510728760000},"page":"432-438","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":145,"title":["Catalytic Transfer Hydrogenation of Biomass\u2010Derived Carbonyls over Hafnium\u2010Based Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"11","author":[{"given":"Sergio","family":"Rojas\u2010Buzo","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica UPV-CSIC Universitat Polit\u00e8cnica de Val\u00e8ncia-Consejo Superior de Investigaciones Cient\u00edficas  Avenida de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pilar","family":"Garc\u00eda\u2010Garc\u00eda","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica UPV-CSIC Universitat Polit\u00e8cnica de Val\u00e8ncia-Consejo Superior de Investigaciones Cient\u00edficas  Avenida de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2232-3527","authenticated-orcid":false,"given":"Avelino","family":"Corma","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica UPV-CSIC Universitat Polit\u00e8cnica de Val\u00e8ncia-Consejo Superior de Investigaciones Cient\u00edficas  Avenida de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,12,21]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050989d"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc41492b"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2016.01.013"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2011.03.014"},{"key":"e_1_2_7_6_1","unstructured":"\u00a0"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY00574A"},{"key":"e_1_2_7_8_2","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1039\/9781849737494-00061","volume":"33","author":"Hara K.","year":"2015","journal-title":"RSC Green Chem. 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