{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,12]],"date-time":"2026-06-12T17:42:01Z","timestamp":1781286121880,"version":"3.54.1"},"reference-count":72,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2017,12,19]],"date-time":"2017-12-19T00:00:00Z","timestamp":1513641600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2018,1,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A diiron benzenedithiolate hydrogen\u2010evolving catalyst immobilized onto fluorine\u2010doped tin oxide (FTO) electrodes is prepared, characterized, and studied in the context of the development of water splitting devices based on molecular components. FTO was chosen as the preferred electrode material owing to its conductive properties and electrochemical stability. An FTO nanocrystalline layer is also used to greatly improve the surface area of commercially available FTO while preserving the properties of the material. Electrodes bearing a covalently anchored diiron catalyst are shown to be competent for electrocatalytic hydrogen evolution from acidic aqueous media at relatively low overpotential (500\u2005mV) with a faradaic efficiency close to unity. Compared with bulk solution catalysts, the catalyst immobilized onto the electrode surface operates at roughly 160\u2005mV lower overpotentials, yet with similar rates.<\/jats:p>","DOI":"10.1002\/cssc.201701757","type":"journal-article","created":{"date-parts":[[2017,10,27]],"date-time":"2017-10-27T11:36:40Z","timestamp":1509104200000},"page":"209-218","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["A Functional Hydrogenase Mimic Chemisorbed onto Fluorine\u2010Doped Tin Oxide Electrodes: A Strategy towards Water Splitting Devices"],"prefix":"10.1002","volume":"11","author":[{"given":"Riccardo","family":"Zaffaroni","sequence":"first","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Remko J.","family":"Detz","sequence":"additional","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jarl Ivar","family":"van\u2005der\u2005Vlugt","sequence":"additional","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5024-508X","authenticated-orcid":false,"given":"Joost N. H.","family":"Reek","sequence":"additional","affiliation":[{"name":"Van't Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,12,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201000293"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0603395103"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0360-3199(02)00022-8"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC46135A"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2013.01.151"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4005814"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M111.305797"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cbpa.2004.02.004"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/bi500210x"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbamcr.2014.11.021"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja073886g"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee03309g"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.crci.2008.04.001"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201500345"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201402918"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic701982z"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2011.06.007"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja309216v"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3094394"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1180"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/om5004013"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1501014"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc00724b"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/b801373j"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200700845"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.04.011"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/om100396j"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00669"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00180"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00209a012"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(99)00013-8"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/B921559J"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201202149"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201207448"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201207448"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40961a"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp5061792"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.5b03136"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC02124C"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03946G"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE02853H"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1179773"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005427"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201005427"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja410592d"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511378"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201511378"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201605066"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja407176p"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201400083"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA04914D"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/b617399c"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/b926749b"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6b00506"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2005.02.019"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/om7003354"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2010.02.112"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2006.06.005"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/om300938e"},{"key":"e_1_2_7_57_1","first-page":"7757","volume":"5","author":"Quentel F.","year":"2012","journal-title":"Phys. Chem. Chem. Phys."},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201884"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1371\/journal.pone.0107942"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2006.07.114"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC00022G"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462207"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462207"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac00106a003"},{"key":"e_1_2_7_64_1","doi-asserted-by":"crossref","first-page":"259","DOI":"10.3891\/acta.chem.scand.35b-0259","volume":"35","author":"Parker V. D.","year":"1981","journal-title":"Acta Chem. Scand."},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja303560c"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.12.023"},{"key":"e_1_2_7_67_1","unstructured":"As the small hydrogen bubbles were observed to remain trapped at the electrode surface the bias potential was applied for 5\u2005min. Subsequently the electrodes were gently shaken to liberate the small bubbles thereafter the headspace was allowed to equilibrate for 30\u2005min before H2was quantified."},{"key":"e_1_2_7_68_1","unstructured":"On the nanostructured FTO the catalyst loading is about 300\u2005times higher than on the flat electrodes although the electrolyte refreshment rate would be slower owing to the intrinsic porosity of the material. As such the combination of these two effects would lead to a more rapid pH change on the nanostructured material and this may lead to quicker decomposition\/desorption of the catalyst explaining the lower TON."}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fcssc.201701757","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.201701757","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T19:09:40Z","timestamp":1760382580000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.201701757"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,12,19]]},"references-count":72,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2018,1,10]]}},"alternative-id":["10.1002\/cssc.201701757"],"URL":"https:\/\/doi.org\/10.1002\/cssc.201701757","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,12,19]]},"assertion":[{"value":"2017-09-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2017-12-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}