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The as\u2010prepared RuP<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>@NPC exhibits a uniform core\u2013shell hollow nanospherical structure with RuP<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> NPs as the core and N,P\u2010codoped carbon (NPC) as the shell. This strategy integrates many advantages of hollow nanostructures, which provide a conductive substrate and the doping of a nonmetal element. At high temperatures, the obtained thin NPC shell can not only protect the highly active phase of RuP<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> NPs from aggregation and corrosion in the electrolyte but also allows variation in the electronic structures to improve the charge\u2010transfer rate greatly by N,P codoping. The optimized RuP<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>@NPC sample at 900\u2009\u00b0C exhibits a Pt\u2010like performance for the hydrogen evolution reaction (HER) and long\u2010term durability in acidic, alkaline, and neutral solutions. The reaction requires a small overpotential of only 51, 74, and 110\u2005mV at 10\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> in 0.5\u2009<jats:sc>m<\/jats:sc> H<jats:sub>2<\/jats:sub>SO<jats:sub>4<\/jats:sub>, 1.0\u2009<jats:sc>m<\/jats:sc> KOH, and 1.0\u2009<jats:sc>m<\/jats:sc> phosphate\u2010buffered saline, respectively. This work provides a new way to design unique phosphide\u2010doped carbon heterostructures through an inorganic\u2013organic hybrid method as excellent electrocatalysts for HER.<\/jats:p>","DOI":"10.1002\/cssc.201702010","type":"journal-article","created":{"date-parts":[[2017,12,14]],"date-time":"2017-12-14T10:17:21Z","timestamp":1513246641000},"page":"743-752","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":97,"title":["Hydrogen Evolution Activity of Ruthenium Phosphides Encapsulated in Nitrogen\u2010 and Phosphorous\u2010Codoped Hollow Carbon Nanospheres"],"prefix":"10.1002","volume":"11","author":[{"given":"Jing\u2010Qi","family":"Chi","sequence":"first","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum (East China)  Qingdao 266580 PR 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