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The synthetic process requires no physical mixing step. The phase transformation pathway from tavorite LiFePO<jats:sub>4<\/jats:sub>OH to olivine LiFePO<jats:sub>4<\/jats:sub> upon calcination was determined by means of the in\u2005situ high\u2010temperature XRD technique. Benefitting from the unique structure of the material, these microspheres can be densely packed together, giving a high tap density of 1.3\u2005g\u2009cm<jats:sup>\u22123<\/jats:sup>, and simultaneously, defectless LiFePO<jats:sub>4<\/jats:sub> primary nanocrystals modified with a highly conductive surface carbon layer and ultrathin rGO provide good electronic and ionic kinetics for fast electron\/Li<jats:sup>+<\/jats:sup> ion transport.<\/jats:p>","DOI":"10.1002\/cssc.201800786","type":"journal-article","created":{"date-parts":[[2018,5,18]],"date-time":"2018-05-18T10:29:54Z","timestamp":1526639394000},"page":"2255-2261","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Self\u2010Assembly of Antisite Defectless nano\u2010LiFePO<sub>4<\/sub>@C\/Reduced Graphene Oxide Microspheres for High\u2010Performance Lithium\u2010Ion 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