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However, its photocurrent density is still very low for photoelectrochemical cell applications. In this work, a crystal face tailored g\u2010CN photoelectrode has been fabricated by a facile thermal vapor deposition method. We use the melamine formaldehyde resin as a new precursor and have successfully fabricated g\u2010CN films. The intensity ratio between two typical peaks (100) and (001) of g\u2010CN is very different from that in the existing literature. The water splitting photocurrent density is as high as 228.2\u2005\u03bcA\u2009cm<jats:sup>\u22122<\/jats:sup>, which is 126.8\u2005times higher than pure g\u2010CN (1.8\u2005\u03bcA\u2009cm<jats:sup>\u22122<\/jats:sup>) at 1.23\u2005V vs. reversible hydrogen electrodes under one sun illumination without sacrificial reagents and co\u2010catalysts. The electrode shows the best performance, compared with the previously reported g\u2010CN photoelectrodes.<\/jats:p>","DOI":"10.1002\/cssc.201801295","type":"journal-article","created":{"date-parts":[[2018,7,2]],"date-time":"2018-07-02T12:22:41Z","timestamp":1530534161000},"page":"2497-2501","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["Crystal\u2010Face Tailored Graphitic Carbon Nitride Films for High\u2010Performance Photoelectrochemical Cells"],"prefix":"10.1002","volume":"11","author":[{"given":"Wei","family":"Xiong","sequence":"first","affiliation":[{"name":"Department of Physics City University of Hong Kong  Hong Kong SAR P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shunwei","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Physics City University of Hong Kong  Hong Kong SAR P.R. 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