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In this study, 4\u2010alkylphenol, formed by breaking the robust C<jats:sub>aryl<\/jats:sub>\u2212OCH<jats:sub>3<\/jats:sub> bonds solely with the retention of other structures in lignin\u2010derived methoxylalkylphenols, was produced selectively over a Co<jats:sub>1<\/jats:sub>\u2013Fe<jats:sub>0.1<\/jats:sub>@NC catalyst from real lignin oil as feedstock, which was obtained by a \u201clignin\u2010first\u201d strategy from either birch or cornstalk. A yield of 64.7 or 88.3\u2005mol\u2009% of 4\u2010propylphenol was obtained if birch lignin oil or eugenol was used as the substrate, respectively. The catalysts were characterized by using methods that include Brunauer\u2013Emmett\u2013Teller measurements, XRD, X\u2010ray photoelectron spectroscopy, high\u2010resolution transmission electron microscopy, high\u2010angle annular dark\u2010field scanning transmission electron microscopy, energy\u2010dispersive X\u2010ray spectroscopy, and temperature\u2010programmed desorption with synchrotron vacuum ultraviolet photoionization mass spectrometry. The results of catalyst characterization and comparison experiments indicated that CoN<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> was the main active phase for demethoxylation and hydrogenation, and the incorporation of Fe weakens the adsorption of 4\u2010propylphenol to the catalyst, which inhibits the excessive hydrogenation of 4\u2010propylphenol. This work shows the potential to produce high\u2010value\u2010added 4\u2010alkylphenol from renewable raw biomass.<\/jats:p>","DOI":"10.1002\/cssc.201901578","type":"journal-article","created":{"date-parts":[[2019,8,27]],"date-time":"2019-08-27T05:45:01Z","timestamp":1566884701000},"page":"4791-4798","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Selective Preparation of 4\u2010Alkylphenol from Lignin\u2010Derived Phenols and Raw Biomass over Magnetic Co\u2013Fe@N\u2010Doped Carbon Catalysts"],"prefix":"10.1002","volume":"12","author":[{"given":"Xiaohao","family":"Liu","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Renewable Energy Guangdong Key Laboratory of New and Renewable Energy Research and Development Guangzhou Institute of Energy Conversion Chinese Academy of Sciences  Guangzhou 510640 P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P.R. 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