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Herein, a novel hybrid non\u2010noble iron\u2010based nanocatalyst (named as FeS<jats:sub>2<\/jats:sub>\/NSC) was developed, which was prepared from biomass as C and N source together with inexpensive Fe(NO<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub> as Fe source through high\u2010temperature pyrolysis in a straightforward and cost\u2010effective procedure. Comprehensive characterization revealed that single\u2010phase pyrite FeS<jats:sub>2<\/jats:sub> nanoparticles with precisely defined composition and uniform size were homogeneously dispersed on N,S\u2010codoped porous carbon with large specific surface area, hierarchical porous channels, and high pore volume. The resultant catalyst FeS<jats:sub>2<\/jats:sub>\/NSC demonstrated good catalytic activity for hydrogenation of functionalized nitroarenes with good tolerance of various functional groups in water as a sustainable and green solvent. Compared with bulk pyrite FeS<jats:sub>2<\/jats:sub> and other non\u2010noble metal\u2010based heterogeneous catalysts reported in the literature, a remarkably enhanced activity was observed under mild reaction conditions. More importantly, FeS<jats:sub>2<\/jats:sub>\/NSC displayed exclusive chemoselectivity for the reduction of nitro groups for nitroarenes bearing varying readily reducible groups.<\/jats:p>","DOI":"10.1002\/cssc.201901867","type":"journal-article","created":{"date-parts":[[2019,8,14]],"date-time":"2019-08-14T10:08:53Z","timestamp":1565777333000},"page":"4636-4644","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Hydrogenation of Functionalized Nitroarenes Catalyzed by Single\u2010Phase Pyrite FeS<sub>2<\/sub> Nanoparticles on N,S\u2010Codoped Porous Carbon"],"prefix":"10.1002","volume":"12","author":[{"given":"Yanan","family":"Duan","sequence":"first","affiliation":[{"name":"Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences  Qingdao 266101 P.R. 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