{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:38:45Z","timestamp":1786977525242,"version":"build-2736575974"},"reference-count":43,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2020,3,24]],"date-time":"2020-03-24T00:00:00Z","timestamp":1585008000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100009052","name":"Hector Fellow Academy","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009052","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2020,4,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Starting from the commercially available dimethyl sulfide\u2010gold(I) chloride complex (DMSAuCl) and diazonium salts in the presence of 2,6\u2010di\u2010\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyl\u20104\u2010methylpyridine as base, symmetric and unsymmetric [C^N^C]Au\n                    <jats:sup>III<\/jats:sup>\n                    Cl complexes were synthesized in a selective, photosensitizer\u2010free, photochemical reaction using blue LED light. This new protocol provides the first mercury\u2010free synthesis of these types of pincer\u2010complexes in moderate\u2010to\u2010excellent yields, starting from a readily available gold(I) precursor. Owing to the extraordinary properties of the target compounds, like excellent luminescence and high anticancer activities, the synthesis of such complexes is a highly active field of research, which might make its way to an industrial application. Owing to the disadvantages of the known protocols, especially the toxicity and the selectivity issues in the case of unsymmetric complexes, avoiding the use of mercury, should further accelerate this ongoing development.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202000310","type":"journal-article","created":{"date-parts":[[2020,3,5]],"date-time":"2020-03-05T07:29:21Z","timestamp":1583393361000},"page":"1986-1990","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Mercury\u2010Free Synthesis of Pincer [C^N^C]Au\n                    <sup>III<\/sup>\n                    Complexes by an Oxidative Addition\/CH Activation Cascade"],"prefix":"10.1002","volume":"13","author":[{"given":"Daniel","family":"Eppel","sequence":"first","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Rudolph","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"Rominger","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6720-8602","authenticated-orcid":false,"given":"A. Stephen K.","family":"Hashmi","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"},{"name":"Chemistry Department Faculty of Science King Abdulaziz University  Jedda 21589 Saudi-Arabia"},{"name":"Heidelberg Center for the Environment (HCE) Universit\u00e4t Heidelberg  Im Neuenheimer Feld 229 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,3,24]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/om980274j"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607225"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201607225"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9027692"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201603841"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00180"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500253"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500253"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja068264u"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic3007519"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301149"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201301149"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC07523H"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201707193"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201707193"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106579d"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04788"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC03636E"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09205"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600117"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00339"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/c001216e"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc21972k"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00132C"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201612583"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201612583"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/sj.jhh.1000896"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201602649"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511487"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201511487"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC02199A"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201700121"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806427"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201806427"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC08227H"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00140a024"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF03214859"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr000436x"},{"key":"e_1_2_2_32_1","unstructured":"CCDC\u20051967188 (3\u2009a) 1967189 (3\u2009b) 1967190 (3\u2009g) and 1967191 (3\u2009i)contain the supplementary crystallographic data for this paper. 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