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This study concerns an efficient solar vapor generator comprised of a light\u2010absorbing and photothermal hybrid compound [Ni(Phen)<jats:sub>3<\/jats:sub>][V<jats:sub>14<\/jats:sub>O<jats:sub>34<\/jats:sub>Cl]Cl (NiV<jats:sub>14<\/jats:sub>) confined in mesoporous and hydrophilic glass (meso\u2010glass). The generator is floated in water by supporting it on a domestic melamine\u2013formaldehyde (MF) foam to ensure evaporation at the water\u2013air interface. The porous structures and poor thermal conductivities of the meso\u2010glass and MF foam contribute to enabling a consistent water supply, strong solar thermal localization, and less heat dissipation and convection. Associated with the strong photothermal role of NiV<jats:sub>14<\/jats:sub>, these synergistic effects lead to a water evaporation rate of 14.38\u2005kg\u2009m<jats:sup>\u22122<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup> with total water evaporation efficiency of 111.4% under 6\u2005suns and a daily solar water purification yield of 42.00\u2005L\u2009m<jats:sup>\u22122<\/jats:sup> under 1\u2005sun irradiation. This solar evaporation system shows great promise for high\u2010efficiency water purification application.<\/jats:p>","DOI":"10.1002\/cssc.202000356","type":"journal-article","created":{"date-parts":[[2020,4,2]],"date-time":"2020-04-02T14:12:21Z","timestamp":1585836741000},"page":"2945-2951","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Efficient Solar Evaporation by [Ni(Phen)<sub>3<\/sub>][V<sub>14<\/sub>O<sub>34<\/sub>Cl]Cl Hybrid Semiconductor Confined in Mesoporous Glass"],"prefix":"10.1002","volume":"13","author":[{"given":"Hongping","family":"Zhang","sequence":"first","affiliation":[{"name":"Hefei National Laboratory for Physical Sciences at the Microscale Fujian Institute of Innovation of Chinese Academy of Sciences School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. 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