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In this contribution, an elaborately designed N\u2010doped carbon\u2010supported CoCu bimetallic catalyst (Co<jats:sub>x<\/jats:sub>Cu<jats:sub>y<\/jats:sub>\u2010NC; <jats:italic>x<\/jats:italic>\/<jats:italic>y=<\/jats:italic>9:1, 7:3, 4:6, which represents the designed molar ratio of Co and Cu in the catalyst), which could offer a desirable FDMC yield of 95\u2009% under mild and base\u2010free conditions (Co<jats:sub>7<\/jats:sub>Cu<jats:sub>3<\/jats:sub>\u2010NC, 2\u2005bar O<jats:sub>2<\/jats:sub>, 80\u2009\u00b0C, 4\u2005h) is described for the oxidative esterification of HMF. Notably, an FDMC formation rate of 6.1\u2005mol<jats:sub>FDMC<\/jats:sub>\u2009mol<jats:sub>Co<\/jats:sub><jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup> was achieved over Co<jats:sub>7<\/jats:sub>Cu<jats:sub>3<\/jats:sub>\u2010NC, which represents the highest catalytic efficiency so far among Co\u2010based catalytic systems. It has been demonstrated that Cu\u2010doping in Co<jats:sub>7<\/jats:sub>Cu<jats:sub>3<\/jats:sub>\u2010NC catalyst brings about more active sites (Co\u2010N<jats:sub>x<\/jats:sub> species) with stronger molecular oxygen activation ability. The increase of surface N content of Co<jats:sub>7<\/jats:sub>Cu<jats:sub>3<\/jats:sub>\u2010NC also improves basicity of the catalyst, which favors the hydrogen abstraction process during the HMF oxidative esterification reaction. These findings may pave an efficient and green way for the synthesis of sustainable bio\u2010based polymer monomers.<\/jats:p>","DOI":"10.1002\/cssc.202000537","type":"journal-article","created":{"date-parts":[[2020,5,25]],"date-time":"2020-05-25T07:20:07Z","timestamp":1590391207000},"page":"4151-4158","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["Oxidative Esterification of 5\u2010Hydroxymethylfurfural with an N\u2010doped Carbon\u2010supported CoCu Bimetallic Catalyst"],"prefix":"10.1002","volume":"13","author":[{"given":"Huai","family":"Liu","sequence":"first","affiliation":[{"name":"College of Energy Xiamen University  Xiamen 361102 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Ding","sequence":"additional","affiliation":[{"name":"College of Energy Xiamen University  Xiamen 361102 P. R. 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