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The highest yield of 2,5\u2010dimethylfuran (more than 98\u2009%) from 5\u2010hydroxymethylfurfural are obtained over bimetallic Cu\u2212Co supported on carbon at 180\u2009\u00b0C under 5\u2005bar hydrogen in 2\u2010propanol and over Ni supported on mesoporous carbon at 200\u2009\u00b0C under 30\u2005bar hydrogen in water in a batch reactor. The desired catalyst should have relatively high metal dispersion and some acidity to facilitate both hydrogenation and hydrogenolysis. However, overhydrogenation and overhydrogenolysis forming 2,5\u2010dimethyltetrahydrofuran and methylfuran, respectively, should be suppressed. Furthermore, a hydrophobic support is more selective than oxide\u2010based support. After a careful adjustment of the residence time in a continuous reactor it is also possible to produce high yields of 2,5\u2010dimethylfuran even over Pt\/C. The main challenges limiting the industrial feasibility of these reactions are relatively low initial reactant concentration, catalyst deactivation by sintering, leaching and coking. In addition to selection of optimum reaction conditions and catalyst properties, kinetic modelling was also summarized.<\/jats:p>","DOI":"10.1002\/cssc.202001927","type":"journal-article","created":{"date-parts":[[2020,9,17]],"date-time":"2020-09-17T14:29:24Z","timestamp":1600352964000},"page":"150-168","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":60,"title":["Catalytic Hydrogenation\/Hydrogenolysis of 5\u2010Hydroxymethylfurfural to 2,5\u2010Dimethylfuran"],"prefix":"10.1002","volume":"14","author":[{"given":"P\u00e4ivi","family":"M\u00e4ki\u2010Arvela","sequence":"first","affiliation":[{"name":"Johan Gadolin Process Chemistry Centre Laboratory of Industrial Chemistry and Reaction Engineering \u00c5bo Akademi University  Turku\/\u00c5bo Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Doris","family":"Ruiz","sequence":"additional","affiliation":[{"name":"Physical Chemistry Department Faculty of Chemical Science University of Concepcion  Casilla 160-C Concepci\u00f3n Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0788-2643","authenticated-orcid":false,"given":"Dmitry Yu.","family":"Murzin","sequence":"additional","affiliation":[{"name":"Johan Gadolin Process Chemistry Centre Laboratory of Industrial Chemistry and Reaction Engineering \u00c5bo Akademi University  Turku\/\u00c5bo Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,10,5]]},"reference":[{"key":"e_1_2_10_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CY01628F"},{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3GC41324A"},{"key":"e_1_2_10_3_1","first-page":"2079","volume":"23","author":"Lei H.","year":"2011","journal-title":"Prog. 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