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Herein, an efficient and sustainable pathway is reported to graft these phenolic compounds onto cellulose nanocrystals (CNCs) <jats:italic>via<\/jats:italic> click\u2010type copper\u2010catalyzed azide\/alkyne cycloaddition (CuAAC) reaction. The successful grafting of the phenolic esters on CNC surface was evidenced by a range of chemical analyses, and the degrees of substitution (DS) of the CNC were found to depend on the structure of the phenolic ester grafted. Moreover, aqueous suspensions of the phenolic ester\u2010grafted CNCs not only strongly absorb in both the UVA and UVB regions, but they also exhibit average to very high photostability. Their wide spectrum UV\u2010absorbing properties and their stability upon exposure to UV are highly influenced by the structure of the phenolic ester, particularly by the extra ester group in <jats:italic>p<\/jats:italic>\u2010hydroxycinnamate diesters. These findings demonstrate that cellulose nanocrystals decorated with such plant\u2010derived and nature\u2010inspired phenolic esters are promising sustainable nanomaterials for anti\u2010UV applications.<\/jats:p>","DOI":"10.1002\/cssc.202002017","type":"journal-article","created":{"date-parts":[[2020,9,21]],"date-time":"2020-09-21T17:24:40Z","timestamp":1600709080000},"page":"6552-6561","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["Grafting Nature\u2010Inspired and Bio\u2010Based Phenolic Esters onto Cellulose Nanocrystals Gives Biomaterials with Photostable Anti\u2010UV Properties"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7959-0837","authenticated-orcid":false,"given":"David","family":"Joram Mendoza","sequence":"first","affiliation":[{"name":"Bioresource Processing Research Institute of Australia (BioPRIA) Department of Chemical Engineering Monash University  Clayton VIC 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4096-1629","authenticated-orcid":false,"given":"Louis M. 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