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These reaction conditions are generally forbidden with these highly reactive main\u2010group organometallic compounds. The correct stoichiometry and nature of the polar organometallic alkylating or arylating reagent allows straightforward synthesis of: highly substituted tertiary alcohols, <jats:italic>\u03b2<\/jats:italic>\u2010hydroxy esters, or symmetric ketones, working always under air and at room temperature. Finally, an unprecedented one\u2010pot\/two\u2010step hybrid protocol is developed through combination of an Al\u2010catalyzed cycloaddition of CO<jats:sub>2<\/jats:sub> and propylene oxide with the concomitant fast addition of RLi reagents to the in\u2005situ and transiently formed cyclic carbonate, thus allowing indirect conversion of CO<jats:sub>2<\/jats:sub> into the desired highly substituted tertiary alcohols without need for isolation or purification of any reaction intermediates.<\/jats:p>","DOI":"10.1002\/cssc.202100262","type":"journal-article","created":{"date-parts":[[2021,3,5]],"date-time":"2021-03-05T07:07:40Z","timestamp":1614928060000},"page":"2084-2092","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Fast Addition of s\u2010Block Organometallic Reagents to CO<sub>2<\/sub>\u2010Derived Cyclic Carbonates at Room Temperature, Under Air, and in 2\u2010Methyltetrahydrofuran"],"prefix":"10.1002","volume":"14","author":[{"given":"David","family":"Elorriaga","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas Universidad de Castilla-La Mancha  13071 Ciudad Real Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3720-9345","authenticated-orcid":false,"given":"Felipe","family":"de la Cruz\u2010Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas Universidad de Castilla-La Mancha  13071 Ciudad Real Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mar\u00eda Jes\u00fas","family":"Rodr\u00edguez\u2010\u00c1lvarez","sequence":"additional","affiliation":[{"name":"Laboratorio de Compuestos Organomet\u00e1licos y Cat\u00e1lisis (Unidad Asociada al CSIC) Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica, (IUQOEM) Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO-CINQA) Facultad de Qu\u00edmica Universidad de Oviedo  33071 Oviedo Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6547-4862","authenticated-orcid":false,"given":"Agust\u00edn","family":"Lara\u2010S\u00e1nchez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2212CINQA) Facultad de Ciencias y Tecnolog\u00edas Qu\u00edmicas Universidad de Castilla-La Mancha  13071 Ciudad Real Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5029-0507","authenticated-orcid":false,"given":"Jos\u00e9 Antonio","family":"Castro\u2010Osma","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Inorg\u00e1nica Org\u00e1nica y Bioqu\u00edmica-Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO-CINQA) Facultad de Farmacia Universidad de Castilla-La Mancha  02071 Albacete Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2266-744X","authenticated-orcid":false,"given":"Joaqu\u00edn","family":"Garc\u00eda\u2010\u00c1lvarez","sequence":"additional","affiliation":[{"name":"Laboratorio de Compuestos Organomet\u00e1licos y Cat\u00e1lisis (Unidad Asociada al CSIC) Departamento de Qu\u00edmica Org\u00e1nica e Inorg\u00e1nica, (IUQOEM) Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO-CINQA) Facultad de Qu\u00edmica Universidad de Oviedo  33071 Oviedo Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,3,23]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","volume-title":"Organolithiums: Selectivity for Synthesis","author":"Clayden J.","year":"2002"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470751879"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400187u"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT01004C"},{"key":"e_1_2_7_6_2","volume-title":"Lithium Compounds in Organic Synthesis-From Fundamentals to Applications","author":"Carl E.","year":"2014"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201700394"},{"key":"e_1_2_7_8_1","unstructured":"For recent reviews\/concept articles covering this topic 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