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Here, a cobalt catalyst was developed for the synthesis of primary amines via reductive amination employing hydrogen as the reducing agent and easy\u2010to\u2010handle ammonia, dissolved in water, as the nitrogen source. The catalyst operates under very mild conditions (1.5\u2005mol% catalyst loading, 50\u2009\u00b0C and 10\u2005bar H<jats:sub>2<\/jats:sub> pressure) and outperforms commercially available noble metal catalysts (Pd, Pt, Ru, Rh, Ir). A broad scope and a very good functional group tolerance were observed. The key for the high activity seemed to be the used support: an N\u2010doped amorphous carbon material with small and turbostratically disordered graphitic domains, which is microporous with a bimodal size distribution and with basic NH functionalities in the pores.<\/jats:p>","DOI":"10.1002\/cssc.202100553","type":"journal-article","created":{"date-parts":[[2021,4,7]],"date-time":"2021-04-07T08:51:55Z","timestamp":1617785515000},"page":"2360-2366","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Co\u2010Catalyzed Synthesis of Primary Amines via Reductive Amination employing Hydrogen under very mild Conditions"],"prefix":"10.1002","volume":"14","author":[{"given":"Matthias","family":"Elfinger","sequence":"first","affiliation":[{"name":"Inorganic Chemistry II \u2013 Catalyst design Sustainable Chemistry Centre University of Bayreuth  95440 Bayreuth Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timon","family":"Sch\u00f6nauer","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry II \u2013 Catalyst design Sustainable Chemistry Centre University of Bayreuth  95440 Bayreuth Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sabrina L. 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