{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T18:28:29Z","timestamp":1772994509050,"version":"3.50.1"},"reference-count":42,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2021,5,2]],"date-time":"2021-05-02T00:00:00Z","timestamp":1619913600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21666011"],"award-info":[{"award-number":["21666011"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2021,6,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Metallic tin (Sn) compounds are viewed as promising candidates for sodium\u2010ion batteries (SIB) anode materials yet suffer from large volume expansion and limited electrode kinetics. Manufacturing rational structure is a crucial factor to achieve high\u2010efficiency sodium storage for SIBs. In this study, nano Sn<jats:sub>2<\/jats:sub>S<jats:sub>3<\/jats:sub> embedded in nitrogenous\u2010carbon compounds (nano\u2010Sn<jats:sub>2<\/jats:sub>S<jats:sub>3<\/jats:sub>\/C) was designed for SIB anode materials via a facile three\u2010step strategy: precipitation, heat treatment and vulcanization with no templating agent. Density functional theory calculations suggested that Sn<jats:sub>2<\/jats:sub>S<jats:sub>3<\/jats:sub> displayed a low Na<jats:sup>+<\/jats:sup> diffusion energy barrier and the Sn\u2212S bonds could be rebuilt during the sodiation\/de\u2010sodiation process. Notably, electrochemical measurements coupled with ex\u2010situ X\u2010ray diffraction and ex\u2010situ transmission electron microscopy were proposed to reveal the underlying Na<jats:sup>+<\/jats:sup> storage mechanisms. Sn<jats:sub>2<\/jats:sub>S<jats:sub>3<\/jats:sub> acted as a high\u2010capacity composition, while the porous nitrogenous\u2010carbon matrix served as a rigid\u2010conductive frame to accommodate the volume expansion and prevented the aggregation of nano Sn<jats:sub>2<\/jats:sub>S<jats:sub>3<\/jats:sub>. The rationally generated architectures benefited greatly in rate capacity and structural stability. As expected, the as\u2010prepared nano Sn<jats:sub>2<\/jats:sub>S<jats:sub>3<\/jats:sub>\/C exhibited remarkable rate capabilities with a specific capacity of 603 and 160\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> under typical conditions at 0.2 and 4\u2005A\u2009g<jats:sup>\u22121<\/jats:sup>, respectively. This work may trigger new enthusiasm for engineering high\u2010performance SIB anode materials.<\/jats:p>","DOI":"10.1002\/cssc.202100615","type":"journal-article","created":{"date-parts":[[2021,4,1]],"date-time":"2021-04-01T09:37:13Z","timestamp":1617269833000},"page":"2383-2392","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Nano Sn<sub>2<\/sub>S<sub>3<\/sub> Embedded in Nitrogenous\u2010Carbon Compounds for Long\u2010Life and High\u2010Rate Cycling Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"14","author":[{"given":"Tianbiao","family":"Zeng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Polymer Materials Engineering Polymer Research Institute of Sichuan University  Chengdu 610065 P. R. China"},{"name":"College of Chemistry and Chemical Engineering Chongqing University of Technology  Chongqing 400054 P. R. 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