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The high performance of the designed POLymeric Ionic TAG (POLITAG)\u2010Pd<jats:sup>0<\/jats:sup>, along with its good selectivity achieved in a copper\u2010free process, also led to a simplified purification procedure allowing the minimization of the waste generated as also proven by the very low E\u2010factor values (1.4\u20135) associated.<\/jats:p>","DOI":"10.1002\/cssc.202101052","type":"journal-article","created":{"date-parts":[[2021,7,9]],"date-time":"2021-07-09T08:18:50Z","timestamp":1625818730000},"page":"3359-3366","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["A Waste\u2010Minimized Approach to Cassar\u2010Heck Reaction Based on POLITAG\u2010Pd<sup>0<\/sup> Heterogeneous Catalyst and Recoverable Acetonitrile Azeotrope"],"prefix":"10.1002","volume":"14","author":[{"given":"Federica","family":"Valentini","sequence":"first","affiliation":[{"name":"Dipartimento di Chimica, Biologia e Biotecnologie Universit\u00e0 degli Studi di Perugia  Via Elce di Sotto, 8 06124 Perugia Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Francesco","family":"Ferlin","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Biologia e Biotecnologie Universit\u00e0 degli Studi di Perugia  Via Elce di Sotto, 8 06124 Perugia Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elena","family":"Tomarelli","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Biologia e Biotecnologie Universit\u00e0 degli Studi di Perugia  Via Elce di Sotto, 8 06124 Perugia Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hamed","family":"Mahmoudi","sequence":"additional","affiliation":[{"name":"Chemistry Department Sharif University of Technology  Tehran P.O Box 11155 3615 Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mojtaba","family":"Bagherzadeh","sequence":"additional","affiliation":[{"name":"Chemistry Department Sharif University of Technology  Tehran P.O Box 11155 3615 Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Massimo","family":"Calamante","sequence":"additional","affiliation":[{"name":"Institute of Chemistry of Organometallic Compounds (CNR-ICCOM)  Via Madonna del Piano 10 50019 Sesto Fiorentino Italy"},{"name":"Department of Chemistry<i>\u201cU. 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