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Hence, the development of more effective and sustainable protocols for their production is highly desired. Among the different methodologies reported for ether synthesis, catalytic reductive alcohol etherifications with carbonyl\u2010based moieties (aldehydes\/ketones and carboxylic acid derivatives) have emerged in the last years as a potential tool. These processes constitute appealing routes for the selective production of both symmetrical and asymmetrical ethers (including O\u2010heterocycles) with an increased molecular complexity. Likewise, ester\u2010to\u2010ether catalytic reductions and hydrogenative alcohol etherifications with CO<jats:sub>2<\/jats:sub> to dialkoxymethanes and other acetals, albeit in less extent, have undergone important advances, too. In this Review, an update of the recent progresses in the area of catalytic reductive alcohol etherifications using carbonyl\u2010based compounds and CO<jats:sub>2<\/jats:sub> have been described with a special focus on organic synthetic applications and catalyst design. Complementarily, recent progress made in catalytic acetal\/ketal\u2010to\u2010ether or ester\u2010to\u2010ether reductions and other related transformations have been also summarized.<\/jats:p>","DOI":"10.1002\/cssc.202101184","type":"journal-article","created":{"date-parts":[[2021,7,8]],"date-time":"2021-07-08T12:17:42Z","timestamp":1625746662000},"page":"3744-3784","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["Catalytic Reductive Alcohol Etherifications with Carbonyl\u2010Based Compounds or CO<sub>2<\/sub> and Related Transformations for the Synthesis of Ether Derivatives"],"prefix":"10.1002","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1761-9275","authenticated-orcid":false,"given":"Carles","family":"Lluna\u2010Gal\u00e1n","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica Universitat Polit\u00e9cnica de Val\u00e8ncia-Consejo Superior Investigaciones Cient\u00edficas (UPV-CSIC)  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1376-5558","authenticated-orcid":false,"given":"Luis","family":"Izquierdo\u2010Aranda","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica Universitat Polit\u00e9cnica de Val\u00e8ncia-Consejo Superior Investigaciones Cient\u00edficas (UPV-CSIC)  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9392-7187","authenticated-orcid":false,"given":"Rosa","family":"Adam","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica Universitat Polit\u00e9cnica de Val\u00e8ncia-Consejo Superior Investigaciones Cient\u00edficas (UPV-CSIC)  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9628-9803","authenticated-orcid":false,"given":"Jose R.","family":"Cabrero\u2010Antonino","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica Universitat Polit\u00e9cnica de Val\u00e8ncia-Consejo Superior Investigaciones Cient\u00edficas (UPV-CSIC)  Avda. de los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,8,3]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020080k"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/0471651540"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201001520"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2md20199b"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5004002"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.2174\/1389557519666190312150132"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201900535"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2019.106308"},{"key":"e_1_2_8_10_1","unstructured":"\u00a0"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1080\/14786445008646627"},{"key":"e_1_2_8_12_2","unstructured":"J. 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