{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T20:28:30Z","timestamp":1790886510710,"version":"4.1.0"},"reference-count":54,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2022,3,7]],"date-time":"2022-03-07T00:00:00Z","timestamp":1646611200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2022,4,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Copper\u2010containing materials based on Ce\u2010 and Ca\u2013Nb\u2010mesocellular foam (MCF) silica supports are prepared, characterized and applied as catalysts for gas\u2010phase reductive condensation of acetone to produce methyl isobutyl ketone (MIBK). The properties of the materials, the interaction of metal species, and their role in the catalytic process are examined by nitrogen physisorption, XRD, XPS, CO<jats:sub>2<\/jats:sub>\u2010TPD, H<jats:sub>2<\/jats:sub>\u2010TPR, and chemisorption of NO and pyridine combined with FTIR spectroscopy. A synergistic interaction of Cu<jats:sup>2+<\/jats:sup>, Cu<jats:sup>0<\/jats:sup>, and CeO<jats:sub>2<\/jats:sub> species incorporated in the MCF support enable the Cu\/Ce\u2010MCF catalyst to yield 34\u2009% of acetone conversion with over 90\u2009% MIBK selectivity at 250\u2009\u00b0C. Moreover, this high catalyst selectivity is maintained during operation for 24\u2005h despite a decline in catalyst activity. The catalytic performance is superior to that of hydroxyapatite\u2010supported Cu and similar previously reported Pd\u2010containing catalysts.<\/jats:p>","DOI":"10.1002\/cssc.202102012","type":"journal-article","created":{"date-parts":[[2022,2,21]],"date-time":"2022-02-21T07:08:34Z","timestamp":1645427314000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Copper Supported on Ceria Mesocellular Foam Silica as an Effective Catalyst for Reductive Condensation of Acetone to Methyl Isobutyl Ketone"],"prefix":"10.1002","volume":"15","author":[{"given":"Kalina","family":"Grzelak","sequence":"first","affiliation":[{"name":"Department of Heterogeneous Catalysis Faculty of Chemistry Adam Mickiewicz University, Pozna\u0144  ul. Uniwersytetu Pozna\u0144skiego 8 61-614 Pozna\u0144 Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2104-5411","authenticated-orcid":false,"given":"Maciej","family":"Trejda","sequence":"additional","affiliation":[{"name":"Department of Heterogeneous Catalysis Faculty of Chemistry Adam Mickiewicz University, Pozna\u0144  ul. Uniwersytetu Pozna\u0144skiego 8 61-614 Pozna\u0144 Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anders","family":"Riisager","sequence":"additional","affiliation":[{"name":"Centre for Catalysis and Sustainable Chemistry Department of Chemistry Technical University of Denmark Kemitorvet, Building 207  2800 Kgs. Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,3,7]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1023\/B:TOCA.0000029802.75155.5a"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2005.08.022"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/0926-860X(94)85105-0"},{"key":"e_1_2_7_4_1","first-page":"171","volume":"54","author":"Bombo\u015f D.","year":"2000","journal-title":"Chem. Pap."},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie100770e"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2018.07.005"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2015.08.018"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2005.03.016"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie0601854"},{"key":"e_1_2_7_10_1","first-page":"7","author":"Hetterley R. D.","year":"2006","journal-title":"Chem. Commun."},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(99)00408-1"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(00)00545-7"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-019-01153-6"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2004.11.008"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1019015325859"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1006\/jcat.2002.3625"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2013.04.017"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-019-01186-x"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cy20021j"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/0926-860X(96)00165-2"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2005.09.029"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2006.10.010"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0921-5093(99)00094-5"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13399-019-00492-4"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00608C"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.11.062"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.03.059"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2016.05.037"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201500593"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cy20805b"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY00124B"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02909"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2021.111169"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2018.05.101"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.02.010"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp3119633"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2016.07.015"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2016.10.028"},{"key":"e_1_2_7_39_1","first-page":"178","volume-title":"Structure and Reactivity of Metals in Zeolite Materials. Structure and Bonding","author":"Ziolek M.","year":"2017"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2010.07.086"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/sia.6239"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2004.05.015"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1027265528877"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ra23491f"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2010.03.038"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfcoat.2012.10.027"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2013.10.016"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2008.08.033"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2012.02.029"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/0927-6513(94)00015-8"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2016.08.129"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA05965B"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2014.09.158"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2005.07.048"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202102012","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.202102012","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202102012","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T03:33:08Z","timestamp":1760412788000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202102012"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3,7]]},"references-count":54,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2022,4,7]]}},"alternative-id":["10.1002\/cssc.202102012"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202102012","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,3,7]]},"assertion":[{"value":"2021-09-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-03-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202102012"}}