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Considering the widespread importance of C\u2212N bonds, the development of greener and more convenient ways to form C\u2212N bonds, especially in late\u2010stage synthesis, has become one of the hottest research goals in synthetic chemistry. Copper\u2010catalyzed radical reactions involving <jats:italic>N<\/jats:italic>\u2010centered radicals have emerged as a sustainable and promising approach to build C\u2212N bonds. As a chemically popular and diverse radical species, <jats:italic>N<\/jats:italic>\u2010centered radicals have been used for all kinds of reactions for C\u2212N bond formation by taking advantage of their inherently incredible reactive flexibility. Copper is also the most abundant and economic catalyst with the most relevant activity for facilitating the synthesis of valuable compounds. Therefore, the aim of the present Review was to illustrate recent and significant advances in C\u2212N bond formation methods and to understand the unique advantages of copper catalysis in the generation of <jats:italic>N<\/jats:italic>\u2010centered radicals since 2016. To provide an ease of understanding for the readers, this Review was organized based on the types of nitrogen sources (amines, amides, sulfonamides, oximes, hydrazones, azides, and <jats:italic>tert<\/jats:italic>\u2010butyl nitrite).<\/jats:p>","DOI":"10.1002\/cssc.202102243","type":"journal-article","created":{"date-parts":[[2021,11,9]],"date-time":"2021-11-09T04:20:12Z","timestamp":1636431612000},"page":"5340-5358","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["Recent Advances in Copper\u2010Catalyzed C\u2212N Bond Formation Involving <i>N<\/i>\u2010Centered Radicals"],"prefix":"10.1002","volume":"14","author":[{"given":"Yan\u2010Nan","family":"Zheng","sequence":"first","affiliation":[{"name":"Key Laboratory of Advanced Mass Spectrometry and Molecular Analysis of Zhejiang Province School of Materials Science and Chemical Engineering Ningbo University  Ningbo Zhejiang 315211 P. R. 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