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Current Haber\u2010Bosch ammonia mass production processes work with a thermally activated iron catalyst needing high pressure. The need for large volumes of hydrogen gas and the continuous operation mode render electrification of Haber\u2010Bosch plants difficult to achieve. Electrochemical solutions at low pressure and temperature are faced with the problematic inertness of the nitrogen molecule on electrodes. Direct reduction of N<jats:sub>2<\/jats:sub> to ammonia is only possible with very reactive chemicals such as lithium metal, the regeneration of which is energy intensive. Here, the attractiveness of an oxidative route for N<jats:sub>2<\/jats:sub> activation was presented. N<jats:sub>2<\/jats:sub> conversion to NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub> in a plasma reactor followed by reduction with H<jats:sub>2<\/jats:sub> on a heterogeneous catalyst at low pressure could be an energy\u2010efficient option for small\u2010scale distributed ammonia production with renewable electricity and without intrinsic CO<jats:sub>2<\/jats:sub> footprint.<\/jats:p>","DOI":"10.1002\/cssc.202102526","type":"journal-article","created":{"date-parts":[[2022,3,14]],"date-time":"2022-03-14T06:03:20Z","timestamp":1647237800000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":56,"title":["Energy\u2010Efficient Small\u2010Scale Ammonia Synthesis Process with Plasma\u2010Enabled Nitrogen Oxidation and Catalytic Reduction of Adsorbed NO<sub><i>x<\/i><\/sub>"],"prefix":"10.1002","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0052-080X","authenticated-orcid":false,"given":"Lander","family":"Hollevoet","sequence":"first","affiliation":[{"name":"Center for Surface Chemistry and Catalysis: Characterization and Application Team KU Leuven  Leuven BE-3001 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0412-7597","authenticated-orcid":false,"given":"Elise","family":"Vervloessem","sequence":"additional","affiliation":[{"name":"Research Group PLASMANT Department of Chemistry University of Antwerp  Wilrijk BE-2610 Belgium"},{"name":"Research Unit Plasma Technology (RUPT) Department of Applied Physics Faculty of Engineering and Architecture Ghent University  Ghent BE-9000 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8059-4464","authenticated-orcid":false,"given":"Yury","family":"Gorbanev","sequence":"additional","affiliation":[{"name":"Research Group PLASMANT Department of Chemistry University of Antwerp  Wilrijk BE-2610 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2255-6419","authenticated-orcid":false,"given":"Anton","family":"Nikiforov","sequence":"additional","affiliation":[{"name":"Research Unit Plasma Technology (RUPT) Department of Applied Physics Faculty of Engineering and Architecture Ghent University  Ghent BE-9000 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7883-5786","authenticated-orcid":false,"given":"Nathalie","family":"De Geyter","sequence":"additional","affiliation":[{"name":"Research Unit Plasma Technology (RUPT) Department of Applied Physics Faculty of Engineering and Architecture Ghent University  Ghent BE-9000 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9875-6460","authenticated-orcid":false,"given":"Annemie","family":"Bogaerts","sequence":"additional","affiliation":[{"name":"Research Group PLASMANT Department of Chemistry University of Antwerp  Wilrijk BE-2610 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9292-2357","authenticated-orcid":false,"given":"Johan A.","family":"Martens","sequence":"additional","affiliation":[{"name":"Center for Surface Chemistry and Catalysis: Characterization and Application Team KU Leuven  Leuven BE-3001 Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,3,25]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE02873K"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.spc.2018.08.001"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.05.001"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19130-z"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE02246B"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-018-0268-z"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC02058C"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1111\/jiec.12996"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b07849"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.11.009"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE03769A"},{"key":"e_1_2_8_12_1","unstructured":"H. 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