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This approach parallelly utilizes Eosin Y or graphite electrodes for the co\u2010catalyst\u2010free oxidative conversion of dihydrodibenzo\u2010oxazepines to oxazepines, followed by L\u2010Proline catalyzed direct Mannich\u2010type reaction with ketones. A series of enantioenriched dihydrodibenzo\u2010oxazepines have been prepared in high yields and enantioselectivity. This method shows substantial advantages over the existing protocols by using potentially safer starting materials and cheap commercially available catalysts.<\/jats:p>","DOI":"10.1002\/cssc.202200415","type":"journal-article","created":{"date-parts":[[2022,3,28]],"date-time":"2022-03-28T04:48:43Z","timestamp":1648442923000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Stereoselective Oxidative Mannich Reaction of Ketones with Dihydrodibenzo\u2010Oxazepines via a Merger of Photoredox\u2010\/Electro\u2010Catalysis with Organocatalysis"],"prefix":"10.1002","volume":"15","author":[{"given":"Yaseen","family":"Hussain","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Jammu Jagti, NH-44, Nagrota Bypass  Jammu 181221, J&amp;K 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