{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T16:03:23Z","timestamp":1785859403095,"version":"3.56.0"},"reference-count":70,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2022,6,22]],"date-time":"2022-06-22T00:00:00Z","timestamp":1655856000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/100007633","name":"Stiftelsen f\u00f6r Milj\u00f6strategisk Forskning","doi-asserted-by":"publisher","award":["2018\/11"],"award-info":[{"award-number":["2018\/11"]}],"id":[{"id":"10.13039\/100007633","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2022,8,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Breaking down lignin into smaller units is the key to generate high value\u2010added products. Nevertheless, dissolving this complex plant polyphenol in an environment\u2010friendly way is often a challenge. Levulinic acid, which is formed during the hydrothermal processing of lignocellulosic biomass, has been shown to efficiently dissolve lignin. Herein, levulinic acid was evaluated as a medium for the reductive electrochemical depolymerization of the lignin macromolecule. Copper was chosen as the electrocatalyst due to the economic feasibility and low activity towards the hydrogen evolution reaction. After depolymerization, high\u2010resolution mass spectrometry and nuclear magnetic resonance spectroscopy revealed lignin\u2010derived monomers and dimers. A predominance of aryl ether and phenolic groups was observed. Depolymerized lignin was further evaluated as an anti\u2010corrosion coating, revealing enhancements on the electrochemical stability of the metal. Via a simple depolymerization process of biomass waste in a biomass\u2010based solvent, a straightforward approach to produce high value\u2010added compounds or tailored biobased materials was demonstrated.<\/jats:p>","DOI":"10.1002\/cssc.202200718","type":"journal-article","created":{"date-parts":[[2022,5,24]],"date-time":"2022-05-24T11:05:44Z","timestamp":1653390344000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Electrochemical Depolymerization of Lignin in a Biomass\u2010based Solvent**"],"prefix":"10.1002","volume":"15","author":[{"given":"M\u00e1rcia G. A.","family":"da Cruz","sequence":"first","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robin","family":"Gueret","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhong","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u0119drzej","family":"Pi\u0105tek","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bj\u00f6rn","family":"Beele","sequence":"additional","affiliation":[{"name":"Inorganic Chemistry Bergische Universit\u00e4t Wuppertal  Gau\u00dfstra\u00dfe 20 42119 Wuppertal Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mika H.","family":"Sipponen","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcella","family":"Frauscher","sequence":"additional","affiliation":[{"name":"AC2T research GmbH  Viktor-Kaplan-Str. 2\/c 2700 Wiener Neustadt Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Serhiy","family":"Budnyk","sequence":"additional","affiliation":[{"name":"AC2T research GmbH  Viktor-Kaplan-Str. 2\/c 2700 Wiener Neustadt Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bruno V. M.","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"},{"name":"Inorganic Chemistry Bergische Universit\u00e4t Wuppertal  Gau\u00dfstra\u00dfe 20 42119 Wuppertal Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4452-1831","authenticated-orcid":false,"given":"Adam","family":"Slabon","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Svante Arrhenius v\u00e4g 16\u2005C 10691 Stockholm Sweden"},{"name":"Inorganic Chemistry Bergische Universit\u00e4t Wuppertal  Gau\u00dfstra\u00dfe 20 42119 Wuppertal Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,6,22]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2020.10.029"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10098-020-01945-5"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c02872"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.1c03705"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2021.126195"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213554"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10786"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2019.111526"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00588"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1080\/17518253.2022.2025462"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1186\/s13068-021-01934-w"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00573"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf7810"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00783-2"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC01812F"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202001187"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202000987"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202001187"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC04127K"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202000987"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2018.05.001"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC01995C"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC02210A"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201801676"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SE00912D"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/B918763B"},{"key":"e_1_2_8_27_1","volume-title":"Green Chemistry: Theory and Practice","author":"Anastas P. T.","year":"1998"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1856988"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biteb.2021.100824"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1080\/02773810701282330"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.15376\/biores.9.2.3660-3687"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2017.04.079"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601795"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2017.03.003"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1080\/02773819708003118"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2020.08.128"},{"key":"e_1_2_8_37_1","volume-title":"Top Value Added Chemicals from Biomass Volume I","author":"Werpy T.","year":"2004"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2020.120167"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2020.08.022"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00253-020-10813-7"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527825028.ch8"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC02513A"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02692"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.3389\/fenrg.2020.565570"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal10060692"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cdc.2020.100417"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b00681"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5GC01008J"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC03982A"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC02782K"},{"key":"e_1_2_8_51_1","first-page":"395","volume-title":"Chemical Catalysts for Biomass Upgrading","author":"Song Y.","year":"2019"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC03597A"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau1567"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jaap.2020.104917"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1080\/17518253.2019.1627428"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2019.01.006"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c07807"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0257-8972(01)01099-4"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2014.06.023"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2015.02.179"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2007.02.079"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2015.11.008"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2021.130279"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.3390\/coatings7090133"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40868-019-00069-w"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.5006\/1.3293580"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2021.106344"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106743"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b06568"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2019.04.010"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202200718","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.202200718","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202200718","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T23:30:40Z","timestamp":1760398240000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202200718"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,6,22]]},"references-count":70,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2022,8,5]]}},"alternative-id":["10.1002\/cssc.202200718"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202200718","archive":["Portico"],"relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2022-9164j","asserted-by":"object"}]},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,6,22]]},"assertion":[{"value":"2022-04-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-06-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202200718"}}