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It is still a great challenge to design and manufacture efficient CO<jats:sub>2<\/jats:sub>RR catalysts for desired products. Producing syngas via CO<jats:sub>2<\/jats:sub>RR is an environmentally friendly way to reduce CO<jats:sub>2<\/jats:sub> in the atmosphere and the dependence on fossil fuels. Herein, a new class of Cu\/In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanoparticles (NPs) with controlled phases and structures were successfully prepared as superior electrocatalysts for CO<jats:sub>2<\/jats:sub>RR, where the CO\/H<jats:sub>2<\/jats:sub> ratios in syngas on Cu\/In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> NPs\/C\u2212H<jats:sub>2<\/jats:sub> remained about 1\u2009:\u20092 at a broad potential range and the total faradaic efficiency of H<jats:sub>2<\/jats:sub> and CO always remained about 90\u2009%. Electronic structural analysis revealed that the excellent performance was attributed to the electronic interaction between amorphous In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> and Cu. This work broadens the horizons for designing and preparing fascinating electrocatalysts for CO<jats:sub>2<\/jats:sub>RR.<\/jats:p>","DOI":"10.1002\/cssc.202201350","type":"journal-article","created":{"date-parts":[[2022,9,23]],"date-time":"2022-09-23T09:40:26Z","timestamp":1663926026000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Amorphization\u2010Activated Copper Indium Core\u2010Shell Nanoparticles for Stable Syngas Production from Electrochemical CO<sub>2<\/sub> Reduction"],"prefix":"10.1002","volume":"15","author":[{"given":"Jieyi","family":"Shen","sequence":"first","affiliation":[{"name":"Key Laboratory of Carbon Materials of Zhejiang Province College of Chemistry and Materials Engineering Wenzhou University  Wenzhou 325035 P. R. 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