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Herein, the effect of phosphonium ionic liquids (PILs) in styrene\u2013butadiene rubber compounds was demonstrated with reduced ZnO loading and no DPG to minimize the environmental footprint of the vulcanization process. The structure and chemistry of PILs were found to be the influencing parameters impelling the cross\u2010linking kinetics, enabling shorter induction times. The generation of active Zn<jats:sup>2+<\/jats:sup> sites by PILs was examined through FTIR spectroscopy, calorimetry, and molecular dynamics simulations. From a tire application perspective, the PILs not only enhanced the cure kinetics but also improved the dynamic\u2013mechanical behavior of the rubber composites. Consequently, the harm caused by TWPs to the atmosphere, fuel intake, and CO<jats:sub>2<\/jats:sub> emissions was minimal, thereby confirming the potential use of PILs in the tire industry.<\/jats:p>","DOI":"10.1002\/cssc.202202309","type":"journal-article","created":{"date-parts":[[2023,2,9]],"date-time":"2023-02-09T05:32:39Z","timestamp":1675920759000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Phosphonium Ionic Liquid\u2010Activated Sulfur Vulcanization: A Way Forward to Reduce Zinc Oxide Levels in Industrial Rubber Formulations"],"prefix":"10.1002","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4267-6805","authenticated-orcid":false,"given":"Mohammad Abdul","family":"Sattar","sequence":"first","affiliation":[{"name":"Colloid and Interface Chemistry Laboratory Department of Chemistry Indian Institute of Technology Madras  Chennai 600036 India"},{"name":"R&amp;D Centre MRF Limited  Chennai 600019 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0754-7055","authenticated-orcid":false,"given":"Archita","family":"Patnaik","sequence":"additional","affiliation":[{"name":"Colloid and Interface Chemistry Laboratory Department of Chemistry Indian Institute of Technology Madras  Chennai 600036 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,3,23]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"crossref","unstructured":"Y. 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