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Electrochemical ammonia synthesis (EAS) with sustainable energy generated electricity and decentralized reactors has been considered as environmentally friendly process. Several nitrogen sources have been considered and intensively studied in experiments and computations. Recently, it has been proposed and demonstrated that nitrogen oxides (NO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>) electroreduction for selective ammonia production is feasible. Fundamental insights on experimental observation are necessary for more rational design of catalysts and reactors in the future. In this concept, we review the theoretical and computational insights of electrochemical nitrogen oxides reduction, particularly, the activity trend over diverse transition metal catalysts and products selectivity at varying potentials. 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