{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,17]],"date-time":"2026-06-17T22:32:56Z","timestamp":1781735576728,"version":"3.54.5"},"reference-count":64,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2023,11,20]],"date-time":"2023-11-20T00:00:00Z","timestamp":1700438400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2024,3,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Amorphous Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> film that naturally exists on any Al substrate is a critical bottleneck for the cyclic performance of metallic Al in rechargeable Al batteries. The so\u2010called electron\/ion insulator Al oxide slows down the anode's activation and hinders Al plating\/stripping. The Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> film induces different surface properties (roughness and microstructure) on the metal. Al foils present two optically different sides (shiny and non\u2010shiny), but their surface properties and influence on plating and stripping have not been studied so far. Compared to the shiny side, the non\u2010shiny one has a higher (~28\u2009%) surface roughness, and its greater concentration of active sites (for Al plating and stripping) yields higher current densities. Immersion pretreatments in Ionic\u2010Liquid\/AlCl<jats:sub>3<\/jats:sub>\u2010based electrolyte with various durations modify the surface properties of each side, forming an electrode\u2010electrolyte interphase layer rich in Al, Cl, and N. The created interphase layer provides more tunneling paths for better Al diffusion upon plating and stripping. After 500 cycles, dendritic Al deposition, generated active sites, and the continuous removal of the Al metal and oxide cause accelerated local corrosion and electrode pulverization. We highlight the mechanical surface properties of cycled Al foil, considering the role of immersion pretreatment and the differences between the two sides.<\/jats:p>","DOI":"10.1002\/cssc.202301142","type":"journal-article","created":{"date-parts":[[2023,10,23]],"date-time":"2023-10-23T10:49:42Z","timestamp":1698058182000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Modification of Al Surface via Acidic Treatment and its Impact on Plating and Stripping"],"prefix":"10.1002","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-8157-7927","authenticated-orcid":false,"given":"Fatemehsadat","family":"Rahide","sequence":"first","affiliation":[{"name":"Institute for Applied Materials (IAM) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Krishnaveni","family":"Palanisamy","sequence":"additional","affiliation":[{"name":"Institute of Analytical and Bioanalytical Chemistry Ulm University  Albert-Einstein-Allee 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-1906-8463","authenticated-orcid":false,"given":"Jackson K.","family":"Flowers","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry (IPC) Karlsruhe Institute of Technology (KIT)  Fritz-Haber Weg 2 76131 Karlsruhe Germany"},{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstr. 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjie","family":"Hao","sequence":"additional","affiliation":[{"name":"Institute for Applied Materials (IAM) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Helge S.","family":"Stein","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry (IPC) Karlsruhe Institute of Technology (KIT)  Fritz-Haber Weg 2 76131 Karlsruhe Germany"},{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstr. 11 89081 Ulm Germany"},{"name":"Department of Chemistry Technical University of Munich  Lichtenbergstr. 4 85748 Garching b. M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6001-0580","authenticated-orcid":false,"given":"Christine","family":"Kranz","sequence":"additional","affiliation":[{"name":"Institute of Analytical and Bioanalytical Chemistry Ulm University  Albert-Einstein-Allee 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5134-7130","authenticated-orcid":false,"given":"Helmut","family":"Ehrenberg","sequence":"additional","affiliation":[{"name":"Institute for Applied Materials (IAM) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"},{"name":"Helmholtz Institute Ulm (HIU)  Helmholtzstr. 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9295-2110","authenticated-orcid":false,"given":"Sonia","family":"Dsoke","sequence":"additional","affiliation":[{"name":"Institute for Applied Materials (IAM) Karlsruhe Institute of Technology (KIT)  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"},{"name":"Fraunhofer Institute for Solar Energy Systems  Heidenhofstr. 2 79110 Freiburg Germany"},{"name":"Department of Sustainable Systems Engineering (INATECH) University of Freiburg  79110 Freiburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,11,20]]},"reference":[{"key":"e_1_2_9_1_1","author":"Dunn B.","year":"2011","journal-title":"Science (1979)"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2010.07.020"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/ente.201800550"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SE00050B"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202102026"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(01)01014-X"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201601357"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2425257"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2014.12.026"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2086512"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma9090719"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2019.10.003"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b07024"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14340"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE01448E"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.09.013"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP08776K"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c05173"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/abbb09"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b07024"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP08776K"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/elan.202100669"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA06187C"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2017.10.002"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b10579"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP08776K"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA06187C"},{"key":"e_1_2_9_28_1","volume":"10","author":"Zhan X.","year":"2020","journal-title":"Adv. Energy Mater."},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2017.10.002"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-019-9492-4"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00178a039"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/0013-4686(88)80205-6"},{"key":"e_1_2_9_33_1","author":"Ma D.","year":"2021","journal-title":"Energy Environ."},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14340"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT02132A"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP08776K"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2010.05.034"},{"key":"e_1_2_9_38_1","author":"Loaiza L. C.","year":"2023","journal-title":"J. Electrochem. Soc."},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6528\/aacd7f"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2670(93)E0550-Q"},{"key":"e_1_2_9_41_1","author":"Sabi N.","year":"2023","journal-title":"Batteries & Supercaps"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/0043-1648(95)06809-0"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC00542F"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b02832"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0021708jes"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/0013-4686(87)85083-1"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/0254-0584(94)90175-9"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/0013-4686(96)00080-1"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.200600095"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2015.09.022"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tsf.2013.11.112"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsadv.2021.100112"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/acb108"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elspec.2005.09.010"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.08.003"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elspec.2020.147034"},{"key":"e_1_2_9_57_1","unstructured":"F. Rahide J.\u2005K. Flowers J. Hao H.\u2005S. Stein H. Ehrenberg S. Dsoke submitted to Journal of The Electrochemical Society and under revision2023."},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1771826"},{"key":"e_1_2_9_59_1","volume":"97","author":"Hoffmann R.","year":"2010","journal-title":"Appl. Phys. Lett."},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11340-021-00733-6"},{"key":"e_1_2_9_61_1","author":"Mandai T.","year":"2015","journal-title":"J. Mater. Chem. A"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1143970"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elspec.2017.12.007"},{"key":"e_1_2_9_64_1","unstructured":"F. Rahide K. Palanisamy J.\u2005K. Flowers J. Hao H.\u2005S. Stein C. Kranz H. Ehrenberg S. Dsoke submitted to ChemSusChem and under revision2023."}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202301142","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T14:11:01Z","timestamp":1760364661000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202301142"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,11,20]]},"references-count":64,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2024,3,8]]}},"alternative-id":["10.1002\/cssc.202301142"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202301142","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,11,20]]},"assertion":[{"value":"2023-08-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-11-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202301142"}}