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In this research, the esterification of various alkylcarbamic acids with alcohols into alkyl <jats:italic>N<\/jats:italic>\u2010alkylcarbamates was demonstrated by using a heterogeneous catalyst as well as the corresponding amine additives. In the model reaction, the esterification of benzylcarbamic acid (BZA\u2010CA) and methanol (MeOH), the target product of methyl <jats:italic>N<\/jats:italic>\u2010benzylcarbamate was obtained in 64\u2009% CO<jats:sub>2<\/jats:sub>\u2010based yield at 413\u2005K in 12\u2005h over a CeO<jats:sub>2<\/jats:sub> catalyst, which also exhibited good reusability. In this catalytic system, the corresponding amine additive (<jats:italic>i.\u2009e<\/jats:italic>., benzylamine for BZA\u2010CA) had the important role in the improvement of CO<jats:sub>2<\/jats:sub>\u2010moiety\u2010based balance, allowing the precise kinetic study, in contrast to the cases without such additive. The detailed kinetic study on the target catalytic system and control systems suggested that BZA\u2010CA underwent the esterification by MeOH directly. The current catalytic system using the combination of CeO<jats:sub>2<\/jats:sub> catalyst and corresponding amine additive was also demonstrated to be applicable to the synthesis of alkyl <jats:italic>N<\/jats:italic>\u2010alkylcarbamates from alkylcarbamic acids and alcohols with short, linear alkyl chains (\u2264C<jats:sub>3<\/jats:sub>).<\/jats:p>","DOI":"10.1002\/cssc.202301436","type":"journal-article","created":{"date-parts":[[2023,12,20]],"date-time":"2023-12-20T07:25:53Z","timestamp":1703057153000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Direct Esterification of Alkylcarbamic Acids with Alcohols over CeO<sub>2<\/sub> Catalyst"],"prefix":"10.1002","volume":"17","author":[{"given":"Shogen","family":"Mihara","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry School of Engineering Tohoku University  6-6-07 Aoba, Aramaki, Aoba-ku Sendai Miyagi 980-8579 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