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However, conventional acetic acid reforming would produce various byproducts, including CO, CH<jats:sub>4<\/jats:sub> and so on. Here, we develop a distinctive method for selective hydrogen production from C\u2212C directional cleavage during acetic acid reforming. Completely different from conventional acetic acid reforming process, acetic acid would react with water over organoruthenium catalyst during its C\u2212C cleavage at low temperature, then produce methanol and formic acid (CH<jats:sub>3<\/jats:sub>COOH+H<jats:sub>2<\/jats:sub>O\u2192CH<jats:sub>3<\/jats:sub>OH+HCOOH). Lastly, methanol and formic acid could further decompose into hydrogen and carbon dioxide over organoruthenium selectively. As a result, there is little CO and CH<jats:sub>4<\/jats:sub> produced in the first step of C\u2212C bond cleavage during acetic acid reforming at 100\u2009\u00b0C. Hydrogen production rate is up to 26.8 mol<jats:sub>H2<\/jats:sub>\/(h<jats:sup>\u22121<\/jats:sup>*mol<jats:sup>\u22121<\/jats:sup><jats:sub>Ru<\/jats:sub>) at 150\u2009\u00b0C through a tandem catalysis. A mechanism for C\u2212C cleavage of acetic acid is proposed based on intermediate product analysis and density functional theory (DFT) calculation. Firstly, the C\u2212C single bond was transformed into C=C double bond by dropping one H atom to organoruthenium. Then the coming H<jats:sub>2<\/jats:sub>O molecule reacted with the C=C bond by an addition reaction, forming methanol and formic acid. This research not only proposes distinctive reaction pathway for hydrogen production from acetic acid reforming, but also provides some inspiration for selective C\u2212C bond cleavage during ethanol reforming.<\/jats:p>","DOI":"10.1002\/cssc.202301532","type":"journal-article","created":{"date-parts":[[2024,2,7]],"date-time":"2024-02-07T02:35:47Z","timestamp":1707273347000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Hydrogen Production through Distinctive C\u2212C Cleavage during Acetic Acid Reforming at Low Temperature"],"prefix":"10.1002","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0731-8842","authenticated-orcid":false,"given":"Yangbin","family":"Shen","sequence":"first","affiliation":[{"name":"Institute of Materials Science and Devices Suzhou University of Science and Technology  Suzhou 215009 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