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The reaction could be realized at room temperature with visible light source and metal\u2010free catalyst. Quinuclidine is employed as an efficient HAT reagent and a range of aliphatic amides is employed as both substrate and solvent in the reaction. This photocatalyzed transformation provides a convenient protocol to afford a board range of <jats:italic>N<\/jats:italic>\u2010benzyl amides.<\/jats:p>","DOI":"10.1002\/cssc.202301585","type":"journal-article","created":{"date-parts":[[2023,12,21]],"date-time":"2023-12-21T10:38:47Z","timestamp":1703155127000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Organo\u2010Photoredox Catalyzed C(sp<sup>3<\/sup>)\u2212H Bond Arylation of Aliphatic Amides"],"prefix":"10.1002","volume":"17","author":[{"given":"Yaping","family":"Yi","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Bioorganic Phosphorus Chemistry &amp; Chemical Biology Department of Chemistry Tsinghua University  Beijing 100084 P. R. 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