{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T01:16:56Z","timestamp":1775870216215,"version":"3.50.1"},"reference-count":45,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2024,1,26]],"date-time":"2024-01-26T00:00:00Z","timestamp":1706227200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22172025"],"award-info":[{"award-number":["22172025"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2024,5,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Methyl formate (MF) is one of the most important chemical commodities, which has a wide range of applications. Due to environmental friendliness, mild reaction conditions, and easy operations, electrosynthesis of MF has garnered increasing attention in recent years. In this work, we reported an electrosynthesis route toward MF in a halide\u2010containing methanol solution. The thorough mechanistic investigations point out that electrosynthesis of MF is accomplished by instant reaction between aldehyde from anodic methanol oxidation, and methoxy bromide (CH<jats:sub>3<\/jats:sub>OBr) that is in\u2010situ generated by reaction of Br<jats:sub>2<\/jats:sub> from anodic oxidation of Br<jats:sup>\u2212<\/jats:sup> with methoxide (CH<jats:sub>3<\/jats:sub>O<jats:sup>\u2212<\/jats:sup>) from cathodic reduction of methanol. This method features high atomic economy only producing valuable MF and hydrogen gas, and shows distinct advantages compared to the reported MF electrosynthesis methods. Even at 200\u2005mA\/cm<jats:sup>2<\/jats:sup>, the faradaic efficiency (FE) of MF remains consistently around 60\u2009% at the anode while a 100\u2009% FE hydrogen gas is produced at the cathode.<\/jats:p>","DOI":"10.1002\/cssc.202301691","type":"journal-article","created":{"date-parts":[[2024,1,9]],"date-time":"2024-01-09T03:24:53Z","timestamp":1704770693000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Anodic Oxidation of Methanol to Formaldehyde Synergizing with a Br<sup>\u2010<\/sup>\/Br<sub>2<\/sub> Redox\u2010Mediated Chemical Route to Produce Methyl Formate"],"prefix":"10.1002","volume":"17","author":[{"given":"Ke\u2010An","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 China Southeast University  Jiangning District Nanjing Jiangsu Province 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