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Since cathode materials are one of the bottlenecks of these batteries, there is much interest in layered lithium\u2010rich manganese oxide\u2010based (LLMO) cathodes which can develop this technology. However, Initial Coulombic Efficiency (ICE) loss, poor rate performance and cycling instability issues are still persistent as problems to be solved for these materials. Recent research shows that water\u2010soluble binders are effective in improving the performance of LLMO materials. Herein, we describe the synthesis, characterisation, and application of a series of water\u2010soluble composites as a binder for LLMO cathodes. The PPy is introduced as part of the binder to improve the electronic conductivity and two different oxidants and various PPy to PSAP ratios were used to optimise the final properties. The electrochemical performance and morphology of the cathodes before and after cycling were investigated and compared with the conventional PVDF binder. The LLMO\u22122c electrode showed excellent charge\u2010discharge performance, especially at 5\u2005C and 10\u2005C rates, and high cycling stability at 0.2\u2005C whilst maintaining a final capacity of 184\u2005mAh\/g after 200\u2005cycles, which is equal to 89.3\u2009% capacity retention.<\/jats:p>","DOI":"10.1002\/cssc.202301799","type":"journal-article","created":{"date-parts":[[2024,1,29]],"date-time":"2024-01-29T14:09:40Z","timestamp":1706537380000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Water\u2010soluble Polypyrrole\u2010Polybis(4\u2010oxy benzene sulfonic acid)phosphazene Composites and Investigation of Their Performance as Cathode Binder in Li\u2010ion Batteries"],"prefix":"10.1002","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8915-4465","authenticated-orcid":false,"given":"Halil","family":"Duyar","sequence":"first","affiliation":[{"name":"Department of Chemistry Gebze Technical University  41400 Gebze Kocaeli"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1083-4896","authenticated-orcid":false,"given":"Elif","family":"B\u00fc\u015fra \u00c7elebi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Gebze Technical University  41400 Gebze Kocaeli"},{"name":"School of Chemistry University of Glasgow"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0489-6081","authenticated-orcid":false,"given":"Emre","family":"G\u00fcney","sequence":"additional","affiliation":[{"name":"Department of Chemistry Gebze Technical University  41400 Gebze Kocaeli"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3614-3770","authenticated-orcid":false,"given":"Ferda","family":"Hac\u0131velio\u011flu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Gebze Technical University  41400 Gebze Kocaeli"},{"name":"School of Chemistry University of Glasgow"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,2,20]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2016.01.046"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202000190"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA04568B"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.04.005"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2020.127927"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA00699B"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202100552"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2018.05.088"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1007\/s41918-019-00032-8"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201601066"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2020.136401"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2019.152060"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2019.02.086"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0601916jes"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym9040150"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2013.11.067"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1155\/2006\/860413"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/ab856b"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02704308"},{"key":"e_1_2_9_20_1","volume":"136","author":"Liu S.","year":"2019","journal-title":"Prog. 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