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Nevertheless, the practical application has been hampered by the dissolution of vanadium in traditional aqueous electrolytes owing to the strong polarity of water molecules. Herein, we propose a hybrid electrolyte made of Zn(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> salt in tetraethylene glycol dimethyl ether (G4) and H<jats:sub>2<\/jats:sub>O solvents to upgrade the cycle life of Zn\/\/K<jats:sub>0.486<\/jats:sub>V<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub> battery. The G4 jointly solvates with Zn<jats:sup>2+<\/jats:sup> ions and replaces a portion of the H<jats:sub>2<\/jats:sub>O molecules in the Zn<jats:sup>2+<\/jats:sup> solvation sheath. It forms a strong bond with H<jats:sub>2<\/jats:sub>O, reducing its activity, and significantly inhibiting vanadium dissolution and water\u2010induced parasitic reaction. Consequently, the optimized electrolyte with H<jats:sub>2<\/jats:sub>O and G4 volume ratio of 5\u2009:\u20095 enhances the cycling stability of Zn\/\/K<jats:sub>0.486<\/jats:sub>V<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub> battery, enabling it to reach up to 600 cycles. In addition, the battery demonstrates a satisfactory reversible capacity of 475.7\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> and excellent rate performance attributed to the moderate ionic conductivity (28.8\u2005mS\u2009cm<jats:sup>\u22121<\/jats:sup>) of the hybrid electrolyte. Last but not least, in the optimized electrolyte, the symmetric Zn\/\/Zn cells deliver a long cycling performance of 400\u2005h, while the asymmetric Zn\/\/Cu cells shows a high average coulombic efficiency of 97.4\u2009%.<\/jats:p>","DOI":"10.1002\/cssc.202301833","type":"journal-article","created":{"date-parts":[[2024,4,2]],"date-time":"2024-04-02T11:52:59Z","timestamp":1712058779000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Ether\u2212Water Co\u2010Solvent Electrolytes Enhanced Vanadium Oxide Cathode Cyclic Behaviors for Zinc Batteries"],"prefix":"10.1002","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4337-0824","authenticated-orcid":false,"given":"Linpo","family":"Li","sequence":"first","affiliation":[{"name":"Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering Henan Normal University  Xinxiang 453007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gang","family":"Jiang","sequence":"additional","affiliation":[{"name":"Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering Henan Normal University  Xinxiang 453007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mengxiang","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering Henan Normal University  Xinxiang 453007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mingyang","family":"Xu","sequence":"additional","affiliation":[{"name":"Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering Henan Normal University  Xinxiang 453007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liyuan","family":"Wang","sequence":"additional","affiliation":[{"name":"Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering Henan Normal University  Xinxiang 453007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jing","family":"Li","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions Ministry of Education, School of Chemistry and Chemical Engineering Henan Normal University  Xinxiang 453007 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mingyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Henan Chaoli New Energy Co., Ltd  Xinxiang 453007 P.R. 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