{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T06:49:12Z","timestamp":1770274152587,"version":"3.49.0"},"reference-count":47,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2024,4,5]],"date-time":"2024-04-05T00:00:00Z","timestamp":1712275200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21871027"],"award-info":[{"award-number":["21871027"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22171020"],"award-info":[{"award-number":["22171020"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2024,8,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The multifunctional derivatization of alcohols has been achieved by the bipyridinium\u2010based conjugated small molecule photocatalysts with redox center and Lewis acid site. Besides exhibiting high activity in the selective generation of aldehydes\/ketones, acids from alcohols through solvent modulation, this system renders the first selective synthesis of esters via an attractive cross\u2010coupling pattern, whose reaction route is significantly different from the traditional condensation of alcohols and acids or esterification from hemiacetals. Following the oxidization of alcohol to aldehyde via bipyridinium\u2010mediated electron and energy transfer, the Lewis acid site of bipyridinium then activates the aldehyde and methanol to obtain the acetal, which further reacts with methanol to generate ester. This method not only demonstrates a clear advantage of bipyridinium in diverse catalytic activities, but also paves the way for designing efficient multifunctional small molecule photocatalysts. This metal\u2010 and additive\u2010free photocatalytic esterification reaction marks a significant advancement towards a more environmentally friendly, cost\u2010effective and green sustainable approach, attributed to the utilization of renewable substrate alcohol and the abundant, low\u2010cost air as the oxidant. The mildness of this esterification reaction condition provides a more suitable alternative for large\u2010scale industrial production of esters.<\/jats:p>","DOI":"10.1002\/cssc.202301911","type":"journal-article","created":{"date-parts":[[2024,3,13]],"date-time":"2024-03-13T04:48:28Z","timestamp":1710305308000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Photocatalyzed Oxidative Tandem Reaction Mediated by Bipyridinium for Multifunctional Derivatization of Alcohols"],"prefix":"10.1002","volume":"17","author":[{"given":"Xin\u2010Rong","family":"Yao","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Meng\u2010Ze","family":"Jia","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao\u2010Li","family":"Miao","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shi\u2010Kai","family":"Yu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yun\u2010Rui","family":"Chen","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jia\u2010Qi","family":"Pan","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6195-8525","authenticated-orcid":false,"given":"Jie","family":"Zhang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectronic\/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 102488 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,4,5]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00105"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00291"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01719"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja403615c"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201201960"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol102753n"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar030146d"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c004357e"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410322"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12722"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008261"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2016.07.018"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.6b02902"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA04838C"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC00145A"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC01393D"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc42075b"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2020.106002"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CP05992J"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04585"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5GC02025E"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja511619c"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2017.06.009"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119618"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2020.11.021"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2012.07.091"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601113"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00227a062"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.10.029"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.121028"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.1c06103"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC03730C"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2GC01321E"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c02771"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4332"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00155C"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201700139"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC01519D"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC02594E"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201800118"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC07571A"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.1c02855"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202100854"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c00481"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c00311"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC05600E"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc40975a"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202301911","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T21:16:27Z","timestamp":1760390187000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202301911"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4,5]]},"references-count":47,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2024,8,12]]}},"alternative-id":["10.1002\/cssc.202301911"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202301911","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,4,5]]},"assertion":[{"value":"2023-12-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-04-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202301911"}}