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Nonetheless, conventional impregnation methods induce strong metal\u2010support interaction (SMSI) between Pd and In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>, which leads to the excessive reduction of In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> and the formation of undesirable PdIn alloy in hydrogen\u2010rich atmospheres. Herein, we innovatively synthesized Pd\/In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanocatalysts by the electrostatic self\u2010assembly process between surface\u2010modified composite precursors with opposite charges. And the organic ligands concurrently serve as Pd nanoparticle protective agents. The resultant Pd\/In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> nanocatalyst demonstrates the homogeneous distribution of Pd nanoparticles with controllable sizes on In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> supports and the limited formation of PdIn alloy. As a result, it exhibits superior selectivity and stability compared to the counterparts synthesized by the conventional impregnation procedure. Typically, it attains a maximum methanol space\u2010time yield of 0.54\u2005g<jats:sub>MeOH<\/jats:sub>\u2009h<jats:sup>\u22121<\/jats:sup>g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup> (300\u2009\u00b0C, 3.5\u2005MPa, 21,000\u2005mL\u2009g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>). Notably, the correlation characterization results reveal the significant effect of small\u2010size, highly dispersed Pd nanoparticles in mitigating MSI. These results provide an alternative strategy for synthesizing highly efficient Pd\/In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> catalysts and offer a new insight into the strong metal\u2010support interaction.<\/jats:p>","DOI":"10.1002\/cssc.202400543","type":"journal-article","created":{"date-parts":[[2024,5,1]],"date-time":"2024-05-01T10:39:10Z","timestamp":1714559950000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Electrostatic Self\u2010Assembly Synthesis of Pd\/In<sub>2<\/sub>O<sub>3<\/sub> Nanocatalysts with Improved Performance Toward CO<sub>2<\/sub> Hydrogenation to Methanol"],"prefix":"10.1002","volume":"17","author":[{"given":"Jingxian","family":"Wu","sequence":"first","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  1295 Dingxi Road Shanghai 200050 P. R. 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