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Despite well\u2010developed industrial processes for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol, the effective use of CO\n                    <jats:sub>2<\/jats:sub>\n                    as a feedstock remains challenging because of the costly requirements of high temperature and reaction pressure. In this paper, we report the methanol synthesis from CO\n                    <jats:sub>2<\/jats:sub>\n                    and hydrogen using a dielectric barrier discharge (DBD) reactor under atmospheric pressure with a nickel\u2010cerium\u2010aluminum mixed oxide (Ni\/Ce\u2212Al MOx) catalyst. The combined use of plasma and the Ni\/Ce\u2212Al MOx catalyst was observed to yield 13.3\u00b10.4\u2009% of methanol, favorably compared to the 2.6\u00b10.5\u2009% yield of the case without catalyst. Microscopy images, selected area electron diffraction patterns, and energy\u2010dispersive X\u2010ray analysis confirmed the presence of fluorite\u2010structured ceria, aluminium, nickel, and nickel oxide particles in the catalyst. The reaction mechanism for the plasma\u2010assisted hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    was hypothesized to involve a carbide formation pathway due to the presence of carbide confirmed by X\u2010ray photoelectron spectroscopic characterization.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202400776","type":"journal-article","created":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T08:29:09Z","timestamp":1727684949000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Plasma\u2010Assisted Synthesis of Methanol Through Hydrogenation of Carbon Dioxide With Non\u2010Noble Metal Mixed Oxide Catalysts"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1063-0164","authenticated-orcid":false,"given":"Deepa","family":"Choudhry","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Nebraska-Lincoln  Lincoln, NE 68588 U.S.A."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-4843-1312","authenticated-orcid":false,"given":"Matthew R.","family":"Winburn","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Nebraska-Lincoln  Lincoln, NE 68588 U.S.A."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-3849-6273","authenticated-orcid":false,"given":"Suchit","family":"Sarin","sequence":"additional","affiliation":[{"name":"Department of Materials and Mechanical Engineering University of Nebraska-Lincoln  Lincoln, NE 68588 U.S.A."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ricardo J.","family":"Chiment\u00e3o","sequence":"additional","affiliation":[{"name":"Departamento de Fisicoqu\u00edmica Facultad de Ciencias Qu\u00edmicas Universidad de Concepci\u00f3n  Concepci\u00f3n, Casilla 160-C Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8210-2833","authenticated-orcid":false,"given":"Chin Li","family":"Cheung","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Nebraska-Lincoln  Lincoln, NE 68588 U.S.A."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,10]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6463\/ab795a"},{"key":"e_1_2_9_2_1","unstructured":"US EPA Sources of Greenhouse Gas Emissions2015 https:\/\/www.epa.gov\/ghgemissions\/sources-greenhouse-gas-emissions(Accessed on March 3 2024 2024)."},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.2113\/gselements.4.5.325"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.petlm.2016.11.003"},{"issue":"2015","key":"e_1_2_9_5_1","volume":"373","author":"Ampelli C.","year":"2037","journal-title":"Philos. 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