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However, challenges persist in effectively controlling the selectivity of long carbon chain ketones in elevated ABE conversion. In this research, a Ca\u2010doped Ni\u2010CaO\u2010SiO<jats:sub>2<\/jats:sub> catalyst was designed and employed to achieve a remarkable conversion of 89.9\u2009% into ketone products from the extracted ABE mixture. The selectivity for C8+ ketones reaches 41.8\u2009%, demonstrating exceptional performance. The reversible phase transition between Ca<jats:sub>2<\/jats:sub>SiO<jats:sub>4<\/jats:sub> and CaCO<jats:sub>3<\/jats:sub> enhances the recyclability, thereby improving the sustainability of the process. Additionally, the trace intermediate 3\u2010hepten\u20102\u2010one was successfully detected using two\u2010dimensional GC\u00d7GC\u2212MS, elucidating the conversion pathway in the catalytic upgrading of the ABE mixture. This finding offers a potential route for the efficient utilization of biomass and the highly selective production of value\u2010added chemicals.<\/jats:p>","DOI":"10.1002\/cssc.202400899","type":"journal-article","created":{"date-parts":[[2024,7,16]],"date-time":"2024-07-16T03:39:53Z","timestamp":1721101193000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Upgrade of Acetone\u2010Butanol\u2010Ethanol Mixture to High\u2010Value Biofuels over Ca\u2010Doped Ni\u2010CaO\u2010SiO<sub>2<\/sub> Catalyst"],"prefix":"10.1002","volume":"18","author":[{"given":"Wenyang","family":"Li","sequence":"first","affiliation":[{"name":"National Energy Research and Development Research Center for Biorefinery Department of Chemical Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yishan","family":"Yang","sequence":"additional","affiliation":[{"name":"National Energy Research and Development Research Center for Biorefinery Department of Chemical Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1115-828X","authenticated-orcid":false,"given":"Huili","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Energy Research and Development Research Center for Biorefinery College of Life Science and Technology Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunming","family":"Fang","sequence":"additional","affiliation":[{"name":"National Energy Research and Development Research Center for Biorefinery Department of Chemical Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,9,6]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.18686\/cest.v1i1.32"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.5b00473"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pecs.2019.04.004"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.energy.2017.07.077"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2015.04.028"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11594"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2016.11.044"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b01837"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202200241"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202300124"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005256"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-43773-3"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA17889D"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07593-0"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.8b05717"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.202000907"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01491K"},{"key":"e_1_2_8_18_1","doi-asserted-by":"crossref","unstructured":"A.\u2005C.\u2005P. 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