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The ligand effect in the Pt shell\u2010alloy core nanocatalysts is known to influence the electrocatalytic reaction in interfacial structure. Herein, we reported the synthesis of ternary Pt@PdRu nanoalloy aerogels with ligand effect of PdRu on Pt\u2010enriched surface through electrochemical cycling. Pt@PdRu aerogels with optimized Pt surface electronic structure exhibited high mass activity and specific activity of Pt@PdRu about 450\u2005mA\u2009mg<jats:sub>Pt<\/jats:sub><jats:sup>\u22121<\/jats:sup> and 1.09\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>, which were 1.4 and 1.6 times than that of commercial Pt\/C. Meanwhile, Pt@PdRu aerogels have higher electrochemical stability comparable to commercial Pt\/C. In\u2010situ FTIR spectra results proved that the glucose oxidation reaction on Pt@PdRu aerogels followed the CO\u2010free direct pathway reaction mechanism and part of the products are CO<jats:sub>2<\/jats:sub> by completed oxidation. Furthermore, the ADGFC with Pt@PdRu ultrathin anode catalyst layer showed a much higher power density of 6.2\u2005mW\u2009cm<jats:sup>\u22122<\/jats:sup> than commercial Pt\/C (3.8\u2005Mw\u2009cm<jats:sup>\u22122<\/jats:sup>). To simulate the blood fuel cell, the Pt@PdRu integrated membrane electrode assembly was exposed to glucose solution and a steady\u2010state open circuit of approximately 0.6\u2005V was achieved by optimizing the glucose concentration in cell system.<\/jats:p>","DOI":"10.1002\/cssc.202401108","type":"journal-article","created":{"date-parts":[[2024,7,18]],"date-time":"2024-07-18T03:45:00Z","timestamp":1721274300000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Ligand Effect of PdRu on Pt\u2010Enriched Surface for Glucose Complete Electro\u2010Oxidation to Carbon Dioxide and Abiotic Direct Glucose Fuel Cells"],"prefix":"10.1002","volume":"18","author":[{"given":"Yichi","family":"Guan","sequence":"first","affiliation":[{"name":"Laboratory of Xinjiang Native Medicinal and Edible Plant Resources Chemistry Kashi University  Kashi 844008 China"},{"name":"School of Chemistry and Chemical Engineering Tianjin University 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