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However, the process of compressing and liquefying CH<jats:sub>4<\/jats:sub> for transport and storage typically results in significant energy losses. In addition, in order to optimize its efficacy as a fuel, the CH<jats:sub>4<\/jats:sub> content of natural gas needs to be increased to a level of at least 97\u2009% to ensure its quality and efficiency in various applications. Metal\u2010organic frameworks (MOFs) represent a novel category of porous materials that possess exceptional capability in modifying pore size and chemical environment, making them ideally suited for the storage of CH<jats:sub>4<\/jats:sub> and the adsorption of propane (C<jats:sub>3<\/jats:sub>H<jats:sub>8<\/jats:sub>), ethane (C<jats:sub>2<\/jats:sub>H<jats:sub>6<\/jats:sub>), carbon dioxide (CO<jats:sub>2<\/jats:sub>), nitrogen (N<jats:sub>2<\/jats:sub>), and hydrogen sulfide (H<jats:sub>2<\/jats:sub>S) to facilitate the purification process of CH<jats:sub>4<\/jats:sub> from natural gas. In this paper, we systematically summarize the mechanism by which MOF materials facilitate the storage of CH<jats:sub>4<\/jats:sub> and the purification of CH<jats:sub>4<\/jats:sub> from natural gas, leveraging the structural characteristics inherent to MOF materials. The focus of further research should also be directed towards the investigation of CH<jats:sub>4<\/jats:sub> storage by flexible MOFs, the resolution of the trade\u2010off dilemma, and the commercial application of MOFs.<\/jats:p>","DOI":"10.1002\/cssc.202401382","type":"journal-article","created":{"date-parts":[[2024,8,28]],"date-time":"2024-08-28T14:03:13Z","timestamp":1724853793000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Methane Storage and Purification of Natural Gas in Metal\u2010Organic Frameworks"],"prefix":"10.1002","volume":"18","author":[{"given":"Wenpeng","family":"Xie","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering China University of Petroleum (East China)  Qingdao 266580 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiuju","family":"Fu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Qilu University of Technology (Shandong Academy of Sciences)  Jinan 250353 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4655-6309","authenticated-orcid":false,"given":"Ling\u2010Zhi","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Shandong University of Science and Technology  Qingdao 266590 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liting","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Qilu University of Technology (Shandong Academy of Sciences)  Jinan 250353 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering China University of Petroleum (East China)  Qingdao 266580 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5352-0953","authenticated-orcid":false,"given":"Xuebo","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering China University of Petroleum (East China)  Qingdao 266580 China"},{"name":"School of Materials Science and Engineering Qilu University of Technology (Shandong Academy of Sciences)  Jinan 250353 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2014.03.030"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4834"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enpol.2017.12.049"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz8881"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.0c01862"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adem.201400038"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature15732"},{"key":"e_1_2_7_8_1","unstructured":"Methane Opportunities for Vehicular Energy. 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