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One of the key parameters in the heterogeneous photocatalytic process is the synthesis of efficient photocatalysts that can accomplish efficient and selective reactions. Selective conversion of lignin can be achieved by using heterojunction photocatalysts which can efficiently separate charge carriers\u2019 and promote selective reactions by band structure modulation. This work details a straightforward approach for synthesizing heterojunction photocatalysts based on Bi<jats:sub>4<\/jats:sub>Ti<jats:sub>3<\/jats:sub>O<jats:sub>12<\/jats:sub> and BiOI involving the hydrothermal and co\u2010precipitation methods. Additionally, the synthesized composites were employed in the selective oxidation of veratryl alcohol, a lignin\u2010derived model compound, to produce high\u2010value\u2010added veratraldehyde. The experimental results showed that the BiOI\/Bi<jats:sub>4<\/jats:sub>Ti<jats:sub>3<\/jats:sub>O<jats:sub>12<\/jats:sub> heterojunction (12.5\u2005mol % BiOI) showed superior activity with a veratraldehyde yield of 5.4 and 27.2 times higher than those of Bi<jats:sub>4<\/jats:sub>Ti<jats:sub>3<\/jats:sub>O<jats:sub>12<\/jats:sub> and BiOI, respectively. The mechanistic studies revealed that the improved activity and selectivity were due to the enhanced charge carriers\u2019 separation and the suppression of reactive oxygen species formation through modulation of band structure. This study allows a green approach to lignin\u2010derived biomass valorization to obtain high\u2010value chemicals.<\/jats:p>","DOI":"10.1002\/cssc.202401489","type":"journal-article","created":{"date-parts":[[2024,9,2]],"date-time":"2024-09-02T22:24:40Z","timestamp":1725315880000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Solar Selective Photooxidation of Veratryl Alcohol by Suppression of Reactive Oxygen Species Through Band Modulation in the BiOI\/Bi<sub>4<\/sub>Ti<sub>3<\/sub>O<sub>12<\/sub> Heterojunction"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3329-4669","authenticated-orcid":false,"given":"J. C.","family":"Murillo\u2010Sierra","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Facultad de Ciencias Naturales Matem\u00e1ticas y del Medio Ambiente Universidad Tecnol\u00f3gica Metropolitana  Las Palmeras 3360 Santiago de Chile Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"R.","family":"Romero","sequence":"additional","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas Departamento de Qu\u00edmica Anal\u00edtica e Inorg\u00e1nica Universidad de Concepci\u00f3n  Edmundo Larenas 129 Concepci\u00f3n Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"V.","family":"Melin","sequence":"additional","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas Departamento de Qu\u00edmica Anal\u00edtica e Inorg\u00e1nica Universidad de Concepci\u00f3n  Edmundo Larenas 129 Concepci\u00f3n Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A.","family":"Henriquez","sequence":"additional","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas Departamento de Qu\u00edmica Anal\u00edtica e Inorg\u00e1nica Universidad de Concepci\u00f3n  Edmundo Larenas 129 Concepci\u00f3n Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"L. F.","family":"Montoya","sequence":"additional","affiliation":[{"name":"Departamento de Ingenier\u00eda Qu\u00edmica, Facultad de Ingenier\u00eda Universidad de Concepci\u00f3n  Concepci\u00f3n Chile"},{"name":"Grupo interdisciplinario de nanotecnolog\u00eda aplicada (GINA) Departamento de ingenier\u00eda de materiales Facultad de Ingenier\u00eda Universidad de Concepci\u00f3n, Edmundo Larenas 315  Concepcion Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"C. H.","family":"Campos","sequence":"additional","affiliation":[{"name":"Departamento de F\u00edsico-Qu\u00edmica Facultad de Ciencias Qu\u00edmicas Universidad de Concepci\u00f3n  Concepci\u00f3n Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"D.","family":"Contreras","sequence":"additional","affiliation":[{"name":"Facultad de Ciencias Qu\u00edmicas Departamento de Qu\u00edmica Anal\u00edtica e Inorg\u00e1nica Universidad de Concepci\u00f3n  Edmundo Larenas 129 Concepci\u00f3n Chile"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,25]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c01606"},{"key":"e_1_2_8_2_1","volume":"331","author":"Zhang Q.","year":"2023","journal-title":"Appl. Catal. B"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900354u"},{"key":"e_1_2_8_4_1","volume":"8","author":"Olmos C. 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