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Yet, the facile synthesis of efficient and stable Fe SAs catalysts is still challenging. Here, we reported a Fe SAs anchored on N\u2010doped mesoporous carbon microspheres (NC) catalyst via spraying drying and pyrolysis processes. The highly active Fe SAs are uniformly distributed on the NC matrix, which prevented the aggregation benefiting from the enhanced Fe\u2212N bonds. Also, the mesoporous carbon structure is favorable for fast electron and mass transfer. The optimized Fe@NC\u20102\u2010900 catalyst shows positive half wave potential (E<jats:sub>1\/2<\/jats:sub>=0.86\u2005V vs reversible hydrogen electrodes (RHE)) and starting potential (E<jats:sub>onset<\/jats:sub>=0.98\u2005V vs RHE) in ORR, which is comparable to the commercial Pt\/C catalyst (E<jats:sub>1\/2<\/jats:sub>=0.87\u2005V, E<jats:sub>onset<\/jats:sub>=1.08\u2005V vs RHE). Outstanding stability with a current retention rate of 92.5\u2009% for 9\u2005hours and good methanol tolerance are achieved. The assembled zinc\u2010air batteries showed good stability up to 500\u2005hours at a current density of 5\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>. This work shows potentials of Fe SAs based catalysts for the practical application in ORR and pave a new avenue for promoting their catalytic performances.<\/jats:p>","DOI":"10.1002\/cssc.202401552","type":"journal-article","created":{"date-parts":[[2024,8,13]],"date-time":"2024-08-13T03:38:48Z","timestamp":1723520328000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Fe Single Atoms Anchored on N\u2010doped Mesoporous Carbon Microspheres for Promoted Oxygen Reduction Reaction"],"prefix":"10.1002","volume":"18","author":[{"given":"Zhuyu","family":"Luo","sequence":"first","affiliation":[{"name":"The Education Ministry Key Lab of Resource Chemistry Joint International Research Laboratory of Resource Chemistry Shanghai Key Laboratory of Rare Earth Functional Materials Shanghai Frontiers Science Center of Biomimetic Catalysis College of Chemistry and Materials Science Shanghai Normal University  Shanghai 200234 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