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In this study, a novel one\u2010pot reaction for the concurrent production of xylonic acid and xylitol from xylose is proposed. This reaction was executed at ambient temperature in the presence of a base, eliminating the need for external gases, by leveraging Pt\u2010supported catalysts. Initial experiments using commercially available metal\u2010supported carbon catalysts validated the superior activity of Pt. However, a notable decline in recycling performance was observed in Pt\/C, which is attributed to the sintering of Pt nanoparticles. In contrast, the synthesized Pt\u2010supported ZrO<jats:sub>2<\/jats:sub> catalysts exhibited enhanced recycling performance because of the strong metal\u2013support interaction between Pt and the ZrO<jats:sub>2<\/jats:sub> support. Furthermore, mechanistic insights and density functional theory calculations show that product desorption involves a significantly higher energy barrier compared to substrate adsorption and hydrogenation, highlighting an efficient transfer hydrogenation mechanism leading to equivalent yields of both xylonic acid and xylitol. This study introduces a promising approach for the simultaneous production of sugar\u2010derived acids and alcohols, with implications for sustainable catalysis and process optimization.<\/jats:p>","DOI":"10.1002\/cssc.202401651","type":"journal-article","created":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T11:16:06Z","timestamp":1735298166000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Simultaneous Coproduction of Xylonic Acid and Xylitol: Leveraging <i>In Situ<\/i> Hydrogen Generation and Utilization from Xylose"],"prefix":"10.1002","volume":"18","author":[{"given":"Ali","family":"Awad","sequence":"first","affiliation":[{"name":"Green Carbon Research Center Korea Research Institute of Chemical Technology  Daejeon 34114 Republic of Korea"},{"name":"Department of Advanced Materials and Chemical Engineering University of Science and Technology  Daejeon 34113 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anil H.","family":"Valekar","sequence":"additional","affiliation":[{"name":"Green Carbon Research Center Korea Research Institute of Chemical Technology  Daejeon 34114 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kyung\u2010Ryul","family":"Oh","sequence":"additional","affiliation":[{"name":"Green Carbon Research Center Korea Research Institute of Chemical Technology  Daejeon 34114 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fajar","family":"Prihatno","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Ulsan  Ulsan 44776 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jaehoon","family":"Jung","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Ulsan  Ulsan 44776 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ajaysing S.","family":"Nimbalkar","sequence":"additional","affiliation":[{"name":"Green Carbon Research Center Korea Research Institute of Chemical Technology  Daejeon 34114 Republic of Korea"},{"name":"Department of Advanced Materials and Chemical Engineering University of Science and Technology  Daejeon 34113 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pravin P.","family":"Upare","sequence":"additional","affiliation":[{"name":"Activon Ltd.  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