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In this work, Sn\u2212Ti mixed oxides are prepared via a green and scalable co\u2010precipitation method. This synthesis procedure allows obtaining homogeneous rutile\u2010phase Sn\u2212Ti mixed oxides with enhanced textural properties and a higher amount of Lewis acid sites. More importantly, the catalytic behavior of these Sn\u2212Ti mixed oxides is investigated by using an aqueous mixture of C<jats:sub>2<\/jats:sub>\u2010C<jats:sub>3<\/jats:sub> representative oxygenated compounds, closer to real industrial conditions and differing from usual individual probe molecules studies performed even in the absence of water. Catalytic experiments combined and correlated with spectroscopic measurements (i.\u2009e., XRD, TEM, FT\u2010IR with pyridine adsorption\u2010desorption and N<jats:sub>2<\/jats:sub> adsorption) are performed to better understand the properties of different Sn\u2212Ti catalysts. These materials show promising results in the condensation of light oxygenated compounds present in aqueous fractions. Homogeneous and robust rutile\u2010phase structures with inherent hydrophobic characteristics turn these Sn\u2212Ti materials into active and highly resistant catalysts capable to transform these low\u2010value oxygenated compounds into a mixture of hydrocarbons and aromatics useful for blending with automotive fuels, especially under complex acidic aqueous environments and moderate process conditions.<\/jats:p>","DOI":"10.1002\/cssc.202401761","type":"journal-article","created":{"date-parts":[[2024,10,14]],"date-time":"2024-10-14T13:04:50Z","timestamp":1728911090000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Rutile\u2010Phase Sn\u2010Ti Mixed Oxides as Acid Catalysts for the Condensation of C<sub>2<\/sub>\u2010C<sub>3<\/sub> Oxygenated Compounds in Water"],"prefix":"10.1002","volume":"18","author":[{"given":"A.","family":"Fern\u00e1ndez\u2010Arroyo","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica (UPV-CSIC) Universitat Polit\u00e8cnica de Val\u00e8ncia. Consejo Superior de Investigaciones Cient\u00edficas.  Avda. Los Naranjos s\/n 46022 Valencia Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1111-2855","authenticated-orcid":false,"given":"Marcelo E.","family":"Domine","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica (UPV-CSIC) Universitat Polit\u00e8cnica de Val\u00e8ncia. Consejo Superior de Investigaciones Cient\u00edficas.  Avda. 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