{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:09:08Z","timestamp":1791727748971,"version":"4.3.4"},"reference-count":36,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2024,10,30]],"date-time":"2024-10-30T00:00:00Z","timestamp":1730246400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Raw mixtures of Rare Earths Elements, REE, recovered by E\u2010waste, were used as catalysts to promote the (stereoselective) synthesis of highly valuable compounds. Y<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>, the major species that is recovered by the E\u2010waste, can be easily converted into the catalytically active Y(OTf)<jats:sub>3<\/jats:sub> that is able to efficiently promote the Michael addition of indoles to benzylidene malonates and the stereoselective Diels\u2010Alder cycloaddition between cyclopentadiene and 4\u2010(<jats:italic>S<\/jats:italic>)\u20103 acryloyl 4\u2010tert\u2010butyl 2\u2010oxazolidinone. Additionally, the raw mixtures were immobilissed onto silica and used to construct packed reactors, resulting in values for Productivity and Space\u2010Time Yields that were significantly higher than those of the corresponding batch conversions. Notably, the prepared cartridge employed in the model Michael reaction maintained its catalytic efficiency for more than 4\u2005days of continuous running.<\/jats:p>","DOI":"10.1002\/cssc.202401787","type":"journal-article","created":{"date-parts":[[2024,9,9]],"date-time":"2024-09-09T22:15:56Z","timestamp":1725920156000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Recycling of Rare Earth Elements: From E\u2010Waste to Stereoselective Catalytic Reactions"],"prefix":"10.1002","volume":"18","author":[{"given":"Emanuela","family":"Donato","sequence":"first","affiliation":[{"name":"Dipartimento di Chimica Universit\u00e0 degli Studi di Milano  Via C. Golgi 19 20133 Milano Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fabrizio","family":"Medici","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica Universit\u00e0 degli Studi di Milano  Via C. Golgi 19 20133 Milano Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valerio","family":"Chiroli","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica Universit\u00e0 degli Studi di Milano  Via C. Golgi 19 20133 Milano Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alessandra","family":"Puglisi","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica Universit\u00e0 degli Studi di Milano  Via C. Golgi 19 20133 Milano Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Rogoli","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technology TU Bergakademie Freiberg  Lessingstr. 45 09599 Freiberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Fr\u00f6hlich","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technology TU Bergakademie Freiberg  Lessingstr. 45 09599 Freiberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Bertau","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technology TU Bergakademie Freiberg  Lessingstr. 45 09599 Freiberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Giuseppe","family":"Zanoni","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica Universit\u00e0 di Pavia  Viale Taramelli Pavia Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9568-9642","authenticated-orcid":false,"given":"Maurizio","family":"Benaglia","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica Universit\u00e0 degli Studi di Milano  Via C. Golgi 19 20133 Milano Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,30]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"EC (European Commission) European Innovation Partnership for Raw Materials 2018 Raw Materials Scoreboard file:\/\/\/C:\/Users\/Utente\/Downloads\/ET0118725ENN.en.pd."},{"issue":"5","key":"e_1_2_7_2_1","first-page":"455","volume":"29","author":"Blanchard B.","year":"1979","journal-title":"Waste Manage. Res."},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1201\/9781420054736"},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","unstructured":"USGS Mineral Commodity Summary \u2013 Rare Earths. U.S. Geol. Surv. Miner. Commod. Summ 2021 https:\/\/doi.org\/10.3133\/mcs2021.","DOI":"10.3133\/mcs2021"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.122790"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.3390\/resources3010123"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2017.12.053"},{"key":"e_1_2_7_8_1","unstructured":"USGS Mineral Commodity Summaries 2021 https:\/\/pubs.usgs.gov\/periodicals\/mcs2021\/mcs2021.pdf."},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2016.06.005"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1177\/0734242X11413327"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1177\/0734242X10379455"},{"key":"e_1_2_7_12_1","unstructured":"T. Nobuhiro S. Masahiro Method of Recycling Fluorescent Substance for Fluorescent Lamp Recycled Fluorescent Lamp and Lighting Apparatus Using Thereof. EP 1138741A2 2001."},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.4144\/rpsj.53.121"},{"key":"e_1_2_7_14_1","unstructured":"R. Otto A. Wojtalewicz-Kasprzak Method for Recovery of Rare Earths from Fluorescent Lamps US 7976798 B2 2011."},{"key":"e_1_2_7_15_1","first-page":"156","volume":"7","author":"Diemer A.","year":"2018","journal-title":"JMS"},{"key":"e_1_2_7_16_1","volume":"2","author":"Lorenz T.","year":"2017","journal-title":"Phys. Sci. Rev."},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2019.04.002"},{"key":"e_1_2_7_18_1","first-page":"1","author":"Palmer L. I.","year":"2012","journal-title":"Encycl. Reagents Org. Synth."},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2019.01.051"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2019.118980"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2020.12.039"},{"key":"e_1_2_7_22_1","unstructured":"M. Bertau P. Fr\u00f6hlich T. Lorenz Verfahren zur R\u00fcckgewinnung Seltener Erden aus Seltene Erden-haltigen Leuchtstoffen. Deutsches Patent DE 10 2014 224 015 2014."},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol0523291"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1055\/a-1532-4763"},{"key":"e_1_2_7_25_1","unstructured":"Catalyst Immobilization: Methods and Applications(Eds: A. Puglisi and M. Benaglia) Wiley-VCH Weinheim 2020."},{"key":"e_1_2_7_26_1","unstructured":"Immobilized Organocatalysts for Enantioselective Continuous Flow Processes C. Rodriguez-Escrich M.\u2005A. Pericas inAsymmetric Organocatalysis: New Strategies Catalysts and Opportunities(Eds: L. Albrecht A. Albrecht L. Dell\u2032Amico) Wiley-VCH Weinheim2023."},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b03416"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c08109"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112797"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tgchem.2023.100032"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202301210"},{"key":"e_1_2_7_32_1","volume-title":"Modelling of Chemical Kinetics and Reactor Design","author":"Kayode Coker A.","year":"2001"},{"key":"e_1_2_7_33_1","volume-title":"Perry\u2032s Chemical Engineers Handbook","author":"Green D. W.","year":"2019"},{"key":"e_1_2_7_34_1","volume-title":"Electronic Waste Management and Treatment Technologies","author":"Majeti M.","year":"2019"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-319-26809-5"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0226-9"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202401787","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T19:49:00Z","timestamp":1760384940000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202401787"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,10,30]]},"references-count":36,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2025,2]]}},"alternative-id":["10.1002\/cssc.202401787"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202401787","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,10,30]]},"assertion":[{"value":"2024-08-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-10-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401787"}}