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To meet this demand, we developed a new Pd precursor for highly efficiently incorporating fine Pd\u2010metal into supports. An atmospherically stable Pd precursor (Pd\u201080) was prepared by thermally promoting the aerobic oxidation of tetrakis(triphenylphosphine)palladium. The physical properties of Pd\u201080 were investigated by NMR spectroscopy, SEM, XPS, solvent\u2010relaxation NMR spectroscopy, and dynamic light scattering (DLS) experiments. We also prepared a cordierite\u2010supported Pd catalyst (Pd\/cordierite) by stirring Pd\u201080 and cordierite powder in chloroform at room temperature. Pd\/cordierite selectively catalyzed the hydrogenation of various reducible functional groups, including alkynes, azides, nitro groups, olefins, CO\n                    <jats:sub>2<\/jats:sub>\n                    Bn,\n                    <jats:italic>N<\/jats:italic>\n                    \u2010Cbz,\n                    <jats:italic>O<\/jats:italic>\n                    \u2010Bn, aromatic ketones, and styrene oxide, in continuous\u2010flow hydrogenation reactions. The Pd\/cordierite\u2010catalyzed continuous\u2010flow hydrogenation of nitrobenzene derivatives afforded the corresponding anilines, with catalytic activities maintained for over 250\u2005h of continuous operation with a turnover number (TON) of 61,090.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202401859","type":"journal-article","created":{"date-parts":[[2024,9,25]],"date-time":"2024-09-25T22:25:16Z","timestamp":1727303116000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Stable and Versatile Pd Precursors for the Preparation of Robust Pd Catalysts Under Continuous\u2010Flow"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-5885-348X","authenticated-orcid":false,"given":"Naoya","family":"Sakurada","sequence":"first","affiliation":[{"name":"Laboratory of Organic Chemistry Gifu Pharmaceutica l University  1\u201325\u20134 Daigaku-nishi Gifu 501\u20131196 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kwihwan","family":"Kobayashi","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry Gifu Pharmaceutica l University  1\u201325\u20134 Daigaku-nishi Gifu 501\u20131196 Japan"},{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Industrial Science and Technology  Central 5, Higashi 1\u20131\u20131 Tsukuba, Ibaraki 305\u20138565 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuka","family":"Abe","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry Gifu Pharmaceutica l University  1\u201325\u20134 Daigaku-nishi Gifu 501\u20131196 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kosuke","family":"Niwa","sequence":"additional","affiliation":[{"name":"NGK INSULATORS, LTD.  2\u201356 Suda-cho Mizuho-ku Nagoya, Aichi 467\u20138530 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takashi","family":"Yokoyama","sequence":"additional","affiliation":[{"name":"NGK INSULATORS, LTD.  2\u201356 Suda-cho Mizuho-ku Nagoya, Aichi 467\u20138530 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6048-5578","authenticated-orcid":false,"given":"Tsuyoshi","family":"Yamada","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry Gifu Pharmaceutica l University  1\u201325\u20134 Daigaku-nishi Gifu 501\u20131196 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1642-3273","authenticated-orcid":false,"given":"Takashi","family":"Ikawa","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry Gifu Pharmaceutica l University  1\u201325\u20134 Daigaku-nishi Gifu 501\u20131196 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2792-6826","authenticated-orcid":false,"given":"Hironao","family":"Sajiki","sequence":"additional","affiliation":[{"name":"Laboratory of Organic Chemistry Gifu Pharmaceutica l University  1\u201325\u20134 Daigaku-nishi Gifu 501\u20131196 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14343"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abl4822"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/B802654H"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500486u"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.acat.2017.10.001"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.3389\/fnano.2022.1062608"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultsonch.2004.01.037"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CP55307H"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp001488t"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/b801754a"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2010.12.003"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.supflu.2006.03.021"},{"key":"e_1_2_7_13_1","doi-asserted-by":"crossref","unstructured":"P.\u2005F. 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